A scandium terminal imido complex: synthesis, structure and DFT studies

被引：146

作者：

Lu, Erli ^{[1
]}

Li, Yuxue ^{[1
]}

Chen, Yaofeng ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 25期

基金：

中国国家自然科学基金;

关键词：

C-H ACTIVATION; MULTIPLE-BOND; URANYL-ION; REACTIVITY; LIGANDS; TANTALUM; AMIDO; ORGANOIMIDO; CHEMISTRY; ELECTRON;

D O I：

10.1039/c002870c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first rare earth metal terminal imido complex has been isolated and structurally characterized. The complex has an extremely short M-N bond length and a nearly linear M-N-C angle. DFT studies showed two p orbitals of N(imido) atom form two bonds with two d orbitals of rare earth metal ion.

引用

页码：4469 / 4471

页数：3

共 43 条

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