The thermodynamic properties of potassium uranoborate

被引：0
|
作者：
Karyakin, NV [1 ]
Chernorukov, NG [1 ]
Knyazev, AV [1 ]
Kortikova, OV [1 ]
Khomyakova, VO [1 ]
Chernorukov, GN [1 ]
机构：
[1] Nizhni Novgorod State Univ, Nizhnii Novgorod 603950, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2003年 / 77卷 / 02期
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The standard enthalpy of formation of crystalline KBUO5 at 298.15 K (-2289.5 +/- 4.5 kJ/mol) was determined by reaction calorimetry, and the heat capacity of KBUO5 in the temperature range 5-300 K was measured by adiabatic vacuum calorimetry. The results were used to calculate the standard entropy [-446.0 +/- 2.1 J/(mol K)] and Gibbs function of formation (-2156.5 +/- 5.0 kJ/mol) of this compound at 298.15 K. The standard thermodynamic functions of potassium uranoborate synthesis and thermal decomposition were determined and analyzed.
引用
收藏
页码：159 / 162
页数：4
相关论文
共 50 条
  • [1] The thermodynamic properties of sodium uranoborate
    Karyakin, N.V.
    Chernorukov, N.G.
    Knyazev, A.V.
    Feoktistov, O.V.
    Alimzhanov, M.I.
    Korneva, M.A.
    Zhurnal Fizicheskoj Khimii, 2002, 76 (03): : 420 - 424
  • [2] The thermodynamic properties of sodium uranoborate
    Karyakin, NV
    Chernorukov, NG
    Knyazev, AV
    Feoktistova, OV
    Alimzhanov, MI
    Korneva, MA
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 2002, 76 (03): : 347 - 350
  • [3] The thermodynamic properties of calcium uranoborate
    Chernorukov, N. G.
    Smirnova, N. N.
    Knyazev, A. V.
    Marochkina, M. N.
    Bykova, T. A.
    Ershova, A. V.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 2006, 80 (01): : 37 - 41
  • [4] The thermodynamic properties of calcium uranoborate
    N. G. Chernorukov
    N. N. Smirnova
    A. V. Knyazev
    M. N. Marochkina
    T. A. Bykova
    A. V. Ershova
    Russian Journal of Physical Chemistry, 2006, 80 : 37 - 41
  • [5] The thermodynamic properties of magnesium uranoborate
    N. G. Chernorukov
    N. N. Smirnova
    A. V. Knyazev
    M. N. Marochkina
    A. V. Ershova
    Russian Journal of Physical Chemistry A, 2007, 81 : 683 - 687
  • [6] The thermodynamic properties of magnesium uranoborate
    Chernorukov, N. G.
    Smirnova, N. N.
    Knyazev, A. V.
    Marochkina, M. N.
    Ershova, A. V.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 81 (05) : 683 - 687
  • [7] The thermodynamic properties of magnesium uranoborate tetrahydrate
    N. G. Chernorukov
    N. N. Smirnova
    A. V. Knyazev
    M. N. Marochkina
    A. V. Ershova
    Russian Journal of Physical Chemistry, 2006, 80 : 1205 - 1209
  • [8] The thermodynamic properties of magnesium uranoborate tetrahydrate
    Chernorukov, N. G.
    Smirnova, N. N.
    Knyazev, A. V.
    Marochkina, M. N.
    Ershova, A. V.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 2006, 80 (08): : 1205 - 1209
  • [9] The Thermodynamic Properties of Barium Uranoborate and Its Dihydrate
    N. G. Chernorukov
    N. N. Smirnova
    A. V. Knyazev
    M. N. Marochkina
    A. V. Ershova
    Russian Journal of Physical Chemistry A, Focus on Chemistry, 2008, 82 : 337 - 342
  • [10] The thermodynamic properties of barium uranoborate and its dihydrate
    Chernorukov, N. G.
    Smirnova, N. N.
    Knyazev, A. V.
    Marochkina, M. N.
    Ershova, A. V.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 82 (03) : 337 - 342
12345