Photorefractive properties of poly(siloxane)-triarylamine-based composites for high-speed applications

被引:28
作者
Wright, D
Gubler, U
Moerner, WE
DeClue, MS
Siegel, JS
机构
[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA
[2] Univ Calif San Diego, Dept Chem, San Diego, CA 92103 USA
关键词
D O I
10.1021/jp027456i
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The photorefractive properties of the hole-transporting polymer poly(methyl-bis-(3-methoxyphenyl)-(4-propylphenyl)amine)siloxane (MM-PSX-TAA) doped with the photorefractive chromophore 4-di(2-methoxyethyl) aminobenzylidene malononitrile (AODCST) are presented and compared with results obtained on similar composites based on poly(n-vinylcarbazole) (PVK). The low intrinsic T-g of the new polymer allows the preparation of samples without additional plasticizers. These composites exhibit good chromophore orientational. mobility and exhibit photorefractive response times in the millisecond range, among the fastest reported to date.
引用
收藏
页码:4732 / 4737
页数:6
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