SnCl4-promoted rearrangement of 2,3-epoxy alcohol derivatives:: stereochemical control of the reaction

被引：16
|
作者：
Kita, Y [1 ]
Matsuda, S [1 ]
Inoguchi, R [1 ]
Ganesh, JK [1 ]
Fujioka, H [1 ]
机构：
[1] Osaka Univ, Grad Sch Pharmaceut Sci, Suita, Osaka 5650871, Japan
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 01期
关键词：
SnCl4-promoted rearrangement; tetrasubstituted-23-epoxy alcohol; stereocontrol; alpha-alkoxy ketone; beta-hydroxy ketone;
D O I：
10.1016/j.tetlet.2004.11.018
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The SnCl4-promoted rearrangement of 2,2,3,3-tetrasubstituted-2,3-epoxy-1-alcohol derivatives proceeded in a regio- and stereo-controlled manner to selectively give two types of rearranged products from a single isomer by changing the protecting group of the alcohol. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：89 / 91
页数：3
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