A catalytically active, charge-neutral Rh(I) zwitterion featuring a P,N-substituted "naked" indenide ligand

被引：49
作者：
Stradiotto, M [1 ]
Cipot, J
McDonald, R
机构：
[1] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4J3, Canada
[2] Univ Alberta, Dept Chem, XRay Crystallog Lab, Edmonton, AB T6G 2G2, Canada
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 19期
关键词：
D O I：
10.1021/ja034543v
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis and characterization of a new class of cationic and zwitterionic Rh(I) complexes, which feature multidentate ligands comprised of donor-functionalized indene or indenide units, are reported. This unusual new ligation strategy provides access to the first charge-neutral [κ2-P,N]Rh(I) zwitterion, a complex that functions as a catalyst for the C-H/Si-H dehydrogenative coupling of styrene and triethylsilane. Copyright © 2003 American Chemical Society.
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页码：5618 / 5619
页数：2
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