Thermochemistry of 4-Cyanopyridine Adducts of Some Bivalent Transition Bromides

被引：2

作者：

Dunstan, P. Oliver ^{[1
]}

机构：

[1] Univ Estadual Campinas, Inst Quim, BR-13084971 Sao Paulo, Brazil

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2010年 / 55卷 / 04期

关键词：

MOLECULAR ADDITION COMPOUNDS; PICOLINE N-OXIDE; METAL BROMIDES; HETEROCYCLIC AMINES; TIN(IV) CHLORIDE; COMPLEXES; CO;

D O I：

10.1021/je9006794

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The adducts [MBr(2)(4-cyanopy)(n)] (where M is Mn(II), Fe(II), Co(II), Ni(II), Cu(II), or Zn(II), 4-cyanopy is 4-cyanopyridine, n = 1 or 2) were synthesized and characterized by melting points, elemental analysis, thermal analysis, and IR spectroscopy From calorimetric studies in solution, the standard enthalpies of formation of the adducts and several thermochemical parameters were determined. The mean standard enthalpies of the metal-nitrogen bonds wet e calculated

引用

页码：1554 / 1557

页数：4

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