Direct conversion of biomass to platform chemicals, catalyzed using a deep eutectic solvent of N,N diethyl ethanol ammonium chloride-oxalic acid in a microwave reactor

被引：23
作者：
Arslanoglu, Alpaslan [1 ]
Sert, Murat [1 ]
机构：
[1] Ege Univ, Dept Chem Engn, TR-35100 Izmir, Turkey
来源：
FUEL | 2019年 / 258卷
关键词：
Biomass; Levulinic acid; 5-Hydroxymethyl furfural; Deep eutectic solvents; Microwave reactor; THERMAL-STABILITY; LIGNOCELLULOSIC BIOMASS; CELLULOSE; SORBITOL;
D O I：
10.1016/j.fuel.2019.116142
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Nowadays, the production of platform chemicals from cellulose is found as promising way to obtain valuable products from renewable sources instead of fossil fuel sources. In this study, conversion of cellulose into valuable products by using deep eutectic solvent as catalyst has been studied. The performance of deep eutectic solvent formed by N,N diethylethanol ammonium chloride and oxalic acid was evaluated for the conversion of cellulose in the microwave reactor. Deep eutectic solvent can be easily formed by mixing hydrogen bond acceptor and hydrogen bond donor at specified ratio. Deep eutectic solvents are found promising for processing of biomass and also to obtain ecofriendly systems due to the green nature of deep eutectic solvents (DES). This study show the applicability of DES formed by N,N diethyl ethanol ammonium chloride and oxalic acid in the conversion of cellulose at a temperature of 150, 160 and 170 degrees C and 2.5, 5.0 and 7.5 reaction time. The maximum C efficiency was achieved as 38.4% at 170 degrees C and 5 min reaction time in microwave reactor.
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页数：9
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共 29 条
[1]   Novel solvent properties of choline chloride/urea mixtures [J].
Abbott, AP ;
Capper, G ;
Davies, DL ;
Rasheed, RK ;
Tambyrajah, V .
CHEMICAL COMMUNICATIONS, 2003, (01) :70-71
[2]   Glycerol-based deep eutectic solvents: Physical properties [J].
AlOmar, Mohamed Khalid ;
Hayyan, Maan ;
Alsaadi, Mohammed Abdulhakim ;
Akib, Shatirah ;
Hayyan, Adeeb ;
Hashim, Mohd Ali .
JOURNAL OF MOLECULAR LIQUIDS, 2016, 215 :98-103
[3]   Electrical conductivity of ammonium and phosphonium based deep eutectic solvents: Measurements and artificial intelligence-based prediction [J].
Bagh, F. S. Ghareh ;
Shahbaz, K. ;
Mjalli, F. S. ;
AlNashef, I. M. ;
Hashim, M. A. .
FLUID PHASE EQUILIBRIA, 2013, 356 :30-37
[4]   Investigation on the Thermal Stability of Deep Eutectic Solvents [J].
Chen Wenjun ;
Xue Zhimin ;
Wang Jinfang ;
Jiang Jingyun ;
Zhao Xinhui ;
Mu Tiancheng .
ACTA PHYSICO-CHIMICA SINICA, 2018, 34 (08) :904-911
[5]   Combined treatments for producing 5-hydroxymethylfurfural (HMF) from lignocellulosic biomass [J].
Chi Van Nguyen ;
Lewis, Daniel ;
Chen, Wen-Hwa ;
Huang, Hsin-Wu ;
ALOthman, Zeid Abdullah ;
Yamauchi, Yusuke ;
Wu, Kevin C. -W. .
CATALYSIS TODAY, 2016, 278 :344-349
[6]   Thermal stability of choline chloride deep eutectic solvents by TGA/FTIR-ATR analysis [J].
Delgado-Mellado, Noemi ;
Larriba, Marcos ;
Navarro, Pablo ;
Rigual, Victoria ;
Ayuso, Miguel ;
Garcia, Julian ;
Rodriguez, Francisco .
JOURNAL OF MOLECULAR LIQUIDS, 2018, 260 :37-43
[7]   Dilute-acid Hydrolysis of Cellulose to Glucose from Sugarcane Bagasse [J].
Dussan, Kelly J. ;
Silva, Debora D. V. ;
Moraes, Elisangela J. C. ;
Arruda, Priscila V. ;
Felipe, Maria G. A. .
IBIC2014: 4TH INTERNATIONAL CONFERENCE ON INDUSTRIAL BIOTECHNOLOGY, 2014, 38 :433-438
[8]   Synthesis of 5-hydroxymethyl furfural from cellulose via a two-step process in polar aprotic solvent [J].
Fan, Guozhi ;
Wang, Yuexin ;
Hu, Zongxiao ;
Yan, Juntao ;
Li, Jianfen ;
Song, Guangsen .
CARBOHYDRATE POLYMERS, 2018, 200 :529-535
[9]   Thermal stability and FT-IR analysis of Phosphonium-based deep eutectic solvents with different hydrogen bond donors [J].
Ghaedi, Hosein ;
Ayoub, Muhammad ;
Sufian, Suriati ;
Lal, Bhajan ;
Uemura, Yoshimitsu .
JOURNAL OF MOLECULAR LIQUIDS, 2017, 242 :395-403
[10]   Catalytic conversion of lignocellulosic biomass into hydrocarbons: A mini review [J].
Han, Xuewang ;
Guo, Yong ;
Liu, Xiaohui ;
Xia, Qineng ;
Wang, Yanqin .
CATALYSIS TODAY, 2019, 319 :2-13
123