Recent research progress on iron- and manganese-based positive electrode materials for rechargeable sodium batteries

被引:211
作者
Yabuuchi, Naoaki [1 ,2 ]
Komaba, Shinichi [1 ,2 ]
机构
[1] Tokyo Univ Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628061, Japan
[2] Kyoto Univ, ESICB, Katsura, Kyoto 6158520, Japan
关键词
sodium batteries; insertion materials; abundant elements; IRON(III) PHOSPHATE PHASE; ELECTRICAL ENERGY-STORAGE; CATHODE MATERIAL; ELECTROCHEMICAL PROPERTIES; CRYSTAL-STRUCTURE; ION BATTERIES; LI-ION; NANOCRYSTALLINE FE3O4; MAGNETIC-PROPERTIES; PRUSSIAN BLUE;
D O I
10.1088/1468-6996/15/4/043501
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Large-scale high-energy batteries with electrode materials made from the Earth-abundant elements are needed to achieve sustainable energy development. On the basis of material abundance, rechargeable sodium batteries with iron-and manganese-based positive electrode materials are the ideal candidates for large-scale batteries. In this review, iron-and manganese-based electrode materials, oxides, phosphates, fluorides, etc, as positive electrodes for rechargeable sodium batteries are reviewed. Iron and manganese compounds with sodium ions provide high structural flexibility. Two layered polymorphs, O3-and P2-type layered structures, show different electrode performance in Na cells related to the different phase transition and sodium migration processes on sodium extraction/insertion. Similar to layered oxides, iron/manganese phosphates and pyrophosphates also provide the different framework structures, which are used as sodium insertion host materials. Electrode performance and reaction mechanisms of the iron-and manganese-based electrode materials in Na cells are described and the similarities and differences with lithium counterparts are also discussed. Together with these results, the possibility of the high-energy battery system with electrode materials made from only Earth-abundant elements is reviewed.
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页数:29
相关论文
共 159 条
[1]   INTERCALATION POSITIVE ELECTRODES FOR RECHARGEABLE SODIUM CELLS [J].
ABRAHAM, KM .
SOLID STATE IONICS, 1982, 7 (03) :199-212
[2]   Preparation of LiFeO2 with alpha-NaFeO2-type structure using a mixed-alkaline hydrothermal method [J].
Ado, K ;
Tabuchi, M ;
Kobayashi, H ;
Kageyama, H ;
Nakamura, O ;
Inaba, Y ;
Kanno, R ;
Takagi, M ;
Takeda, Y .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (07) :L177-L180
[3]  
[Anonymous], 1988, Practical handbook of physical properties of rocks and minerals
[4]   Cathode performance and voltage estimation of metal trihalides [J].
Arai, H ;
Okada, S ;
Sakurai, Y ;
Yamaki, J .
JOURNAL OF POWER SOURCES, 1997, 68 (02) :716-719
[5]   Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries [J].
Armstrong, AR ;
Bruce, PG .
NATURE, 1996, 381 (6582) :499-500
[6]  
ARNOLD H, 1982, Z KRISTALLOGR, V159, P10
[7]   Formation and diffusion of vacancy-polaron complex in olivine-type LiMnPO4 and LiFePO4 [J].
Asari, Yusuke ;
Suwa, Yuji ;
Hamada, Tomoyuki .
PHYSICAL REVIEW B, 2011, 84 (13)
[8]   Magnetic Structures of NaFePO4 Maricite and Triphylite Polymorphs for Sodium-Ion Batteries [J].
Avdeev, Maxim ;
Mohamed, Zakiah ;
Ling, Chris D. ;
Lu, Jiechen ;
Tamaru, Mao ;
Yamada, Atsuo ;
Barpanda, Prabeer .
INORGANIC CHEMISTRY, 2013, 52 (15) :8685-8693
[9]   Carbon metal fluoride nanocomposites - High-capacity reversible metal fluoride conversion materials as rechargeable positive electrodes for Li batteries [J].
Badway, F ;
Cosandey, F ;
Pereira, N ;
Amatucci, GG .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (10) :A1318-A1327
[10]   A new polymorph of Na2MnP2O7 as a 3.6 V cathode material for sodium-ion batteries [J].
Barpanda, Prabeer ;
Ye, Tian ;
Avdeev, Maxim ;
Chung, Sai-Cheong ;
Yamada, Atsuo .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (13) :4194-4197