Self-reinforced biodegradable Mg-2Zn alloy wires/polylactic acid composite for orthopedic implants

被引：27

作者：

Cai, Hong ^{[1
,2
]}

Zhang, Yue ^{[1
,2
]}

Li, Xuan ^{[3
]}

Meng, Jiao ^{[1
,2
]}

Xue, Feng ^{[1
,2
]}

Chu, Chenglin ^{[1
,2
]}

Tao, Li ^{[1
,2
]}

Bai, Jing ^{[1
,2
]}

机构：

[1] Southeast Univ, Sch Mat Sci & Engn, Nanjing 211189, Jiangsu, Peoples R China

[2] Jiangsu Key Lab Adv Metall Mat, Nanjing 211189, Jiangsu, Peoples R China

[3] Nanjing Inst Technol, Nanjing 211189, Jiangsu, Peoples R China

来源：

COMPOSITES SCIENCE AND TECHNOLOGY | 2018年 / 162卷

基金：

中国国家自然科学基金;

关键词：

Polymer-matrix composites (PMCs); Interface; Mechanical properties; Surface treatments; Deformation; HYDROXYAPATITE HA PARTICLES; CORTICAL BONE OSTEOTOMIES; SOLID-STATE EXTRUSION; IN-VITRO DEGRADATION; L-LACTIDE PLLA; BIORESORBABLE DEVICES; STRENGTH RETENTION; FORGED COMPOSITES; MAGNESIUM; POLY(L-LACTIDE);

D O I：

10.1016/j.compscitech.2018.04.040

中图分类号：

TB33 [复合材料];

学科分类号：

摘要：

Biodegradable composite rods with polylactic acid as matrix and Mg-2Zn wires as the reinforcement body were prepared by hot press and hot drawn method in this article. The main purpose is to improve the mechanical properties based on the strengthen and toughness effect of the directionally distributed Mg-2Zn wires in PLA matrix and the improved interfacial bonding strength by MAO treated Mg-2Zn wires as well as the self-reinforcement effect of PLA after hot drawn process. The effect of hot drawn on the orientation, crystallinity and melting temperature changes of PLA were investigated by XRD and DSC method. The relationship between the bending strength and the volume content of Mg-2Zn wires in the composite rods as well as the influence of hot drawn on the mechanical properties were compared and analyzed theoretically. The regularly arrangement of PLA chains after hot drawn is benefit to increase the crystallinity, the elastic modulus as well as the mechanical strength in essence. Theoretical calculation results could provide a reference value and guide us to adjust the Mg-2Zn wires content and prepare the composite rods according to the actual application requirements.

引用

页码：198 / 205

页数：8

共 39 条

[1] Effect of compressive strength and tensile reinforcement ratio on flexural behavior of high-strength concrete beams [J].

Ashour, SA .

ENGINEERING STRUCTURES, 2000, 22 (05) :413-423

[2] LATE DEGRADATION TISSUE-RESPONSE TO POLY(L-LACTIDE) BONE PLATES AND SCREWS [J].

BERGSMA, JE ;

DEBRUIJN, WC ;

ROZEMA, FR ;

BOS, RRM ;

BOERING, G .

BIOMATERIALS, 1995, 16 (01) :25-31

[3] STRENGTH RATIOS OF COMPOSITE-MATERIALS IN FLEXURE AND IN TENSION [J].

BULLOCK, RE .

JOURNAL OF COMPOSITE MATERIALS, 1974, 8 (APR) :200-206

[4] Recent advances on the development of biodegradable magnesium alloys: a review [J].

Chen, Junxiu ;

Tan, Lili ;

Yang, Ke .

MATERIALS TECHNOLOGY, 2016, 31 (12) :681-688

[5] High-purity magnesium interference screws promote fibrocartilaginous entheses regeneration in the anterior cruciate ligament reconstruction rabbit model via accumulation of BMP-2 and VEGF [J].

Cheng, Pengfei ;

Han, Pei ;

Zhao, Changli ;

Zhang, Shaoxiang ;

Wu, Hongliu ;

Ni, Jiahua ;

Hou, Peng ;

Zhang, Yuanzhuang ;

Liu, Jingyi ;

Xu, Haidong ;

Liu, Shen ;

Zhang, Xiaonong ;

Zheng, Yufeng ;

Chai, Yimin .

BIOMATERIALS, 2016, 81 :14-26

[6] In vitro degradation of biodegradable polylactic acid/magnesium composites: Relevance of Mg particle shape [J].

Cifuentes, S. C. ;

Gavilan, R. ;

Lieblich, M. ;

Benavente, R. ;

Gonzalez-Carrasco, J. L. .

ACTA BIOMATERIALIA, 2016, 32 :348-357

[7] Magnesium from bioresorbable implants: Distribution and impact on the nano- and mineral structure of bone [J].

Gruenewald, T. A. ;

Rennhofer, H. ;

Hesse, B. ;

Burghammer, M. ;

Stanzl-Tschegg, S. E. ;

Cotte, M. ;

Loeffler, J. F. ;

Weinberg, A. M. ;

Lichtenegger, H. C. .

BIOMATERIALS, 2016, 76 :250-260

[8] Tailoring the degradation and biological response of a magnesium-strontium alloy for potential bone substitute application [J].

Han, Junjie ;

Wan, Peng ;

Ge, Ye ;

Fan, Xinmin ;

Tan, Lili ;

Li, Jianjun ;

Yang, Ke .

MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2016, 58 :799-811

[9] Hydrostatic extrusion of poly(L-lactide) [J].

Jin, FZ ;

Moon, SI ;

Tsutsumi, S ;

Hyon, SH .

MACROMOLECULAR SYMPOSIA, 2005, 224 :93-104

[10] Strength retention of self-reinforced drawn poly-L/DL-lactide 70/30 (SR-PLA70) rods and fixation properties of distal femoral osteotomies with these rods.: An experimental study on rats [J].

Joukainen, A ;

Pihlajamäki, H ;

Mäkelä, EA ;

Ashammakhi, N ;

Viljanen, J ;

Pätiälä, H ;

Kellomäki, M ;

Törmälä, P ;

Rokkanen, P .

JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION, 2000, 11 (12) :1411-1428

← 1 2 3 4 →