Heat capacities, excess enthalpies, and volumes of mixtures containing cyclic ethers. 2. Binary systems 1,3-dioxolane plus n-alkanes

被引:52
作者
Brocos, P
Calvo, E
Amigo, A
Bravo, R [1 ]
Pintos, M
Roux, AH
Roux-Desgranges, G
机构
[1] Univ Santiago, Fac Fis, Dept Fis Aplicada, E-15706 Santiago De Compostela, Spain
[2] Univ Blaise Pascal, Lab Thermodynam & Genie Chim, F-63177 Aubiere, France
关键词
D O I
10.1021/je9701947
中图分类号
O414.1 [热力学];
学科分类号
摘要
Excess molar volumes for {1,3-dioxolane + heptane, octane, nonane, and decane} at the temperatures 288.15 K, 298.15 K, and 308.15 K, excess molar enthalpies for {1,3-dioxolane + heptane, octane, nonane, decane, dodecane, and tetradecane} at the temperature 298.15 K, and isobaric excess molar heat capacities for {1,3-dioxolane + heptane, octane, nonane, and decane} at the temperature 298.15 K have been determined as a function of mole fraction. The magnitude of these experimental quantities is discussed in terms of the nature and type of intermolecular interactions in binary mixtures.
引用
收藏
页码:112 / 116
页数:5
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