Preferential growth of perovskite BaTiO3 thin films on Gd3Ga5O12(100) and Y3Fe5O12(100) oriented substrates by pulsed laser deposition

被引:2
|
作者
Ruf, Thomas [1 ]
Merker, Stefan [2 ]
Syrowatka, Frank [3 ]
Trempler, Philip [4 ]
Schmidt, Georg [4 ]
Lorenz, Michael [5 ]
Grundmann, Marius [5 ]
Denecke, Reinhard [1 ]
机构
[1] Wilhelm Ostwald Inst Phys & Theoret Chem, Linnestr 2, D-04103 Leipzig, Germany
[2] Univ, Inst Anorgan Chem, Johannisallee 29, D-04103 Leipzig, Germany
[3] Martin Luther Univ Halle Wittenberg, Interdisziplinares Zentrum Mat Wissensch, Heinrich Damerow Str 4, D-06120 Halle, Germany
[4] Martin Luther Univ Halle Wittenberg, Inst Phys, Von Danckelmann Pl 3, D-06120 Halle, Germany
[5] Univ Leipzig, Felix Bloch Inst Festkorperphys, Linnestr 5, D-04103 Leipzig, Germany
来源
MATERIALS ADVANCES | 2022年 / 3卷 / 12期
关键词
BARIUM-TITANATE; CRYSTAL; SURFACE;
D O I
10.1039/d2ma00041e
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This growth study is concerned with the structural compatibility of perovskite BaTiO3 on garnet substrates Gd3Ga5O12 and Y3Fe5O12. Thin films (200 and 500 nm nominal thickness) have been deposited by pulsed laser deposition on the low-index orientations (100), (110) and (111) of Gd3Ga5O12 single crystal substrates, as well as on a selection of Y3Fe5O12 surfaces. The perovskite growth on the garnet (100) orientation exhibits good crystallinity as observed as higher X-ray diffraction intensities, (110)/(101) preferential growth and weak "rectangle-on-cube" in-plane epitaxy of the BaTiO3 thin film. In contrast to that for growth on the (110) and (111) garnet substrates only polycrystalline BaTiO3 thin films are observed. For X-ray photoelectron spectroscopy measurements, a scheme is presented for chemical analysis of a BaTiO3 bulk and a surface component, and quantification of the surface concentration of the films is presented. A surface contamination of Bi traces seems to affect the strain on the BaTiO3(110) reflex.
引用
收藏
页码:4920 / 4931
页数:12
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