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Synthesis and spectroscopic studies of some halogen-dimethylsulphoxide/tetramethylenesulphoxideruthenium(II) and ruthenium(III) complexes with 2-aminobenzimidazole
被引:5
|作者:
Shukla, Satyendra N.
[1
]
Gaur, Pratiksha
[1
]
Kaur, Harpreet
[1
]
Prasad, Mahender
[1
]
机构:
[1] Govt Model Sci Coll, Coordinat Chem Res Lab, Dept Chem, Jabalpur 482001, Madhya Pradesh, India
关键词:
ruthenium;
dimethylsulphoxide;
tetramethylenesulphoxide;
aminobenzimidazole;
D O I:
10.1080/00958970600990606
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Synthesis and characterization of seven ruthenium(II) and ruthenium(III) complexes of sulphoxide with 2-aminobenzimidazole are reported. Three different formulations exist; [cis-RuCl2(SO)(3)(2-ABZ)]; [trans-RuCl2(SO)(3))(2-ABZ)]; and [trans-RuCl4(SO)(2-ABZ (where SO dimethylsulphoxide(DMSO)/tetramethylenesulphoxide(TMSO); 2-ABZ 2-aminobenzimidazole). These complexes are characterized by elemental analysis, conductivity magnetic susceptibility, H-1-NMR, C-13{H-1}-NMR and electronic spectroscopy.
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页码:1047 / 1055
页数:9
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