Synthesis and spectroscopic studies of some halogen-dimethylsulphoxide/tetramethylenesulphoxideruthenium(II) and ruthenium(III) complexes with 2-aminobenzimidazole

被引：5
|
作者：
Shukla, Satyendra N. [1 ]
Gaur, Pratiksha [1 ]
Kaur, Harpreet [1 ]
Prasad, Mahender [1 ]
机构：
[1] Govt Model Sci Coll, Coordinat Chem Res Lab, Dept Chem, Jabalpur 482001, Madhya Pradesh, India
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 60卷 / 10期
关键词：
ruthenium; dimethylsulphoxide; tetramethylenesulphoxide; aminobenzimidazole;
D O I：
10.1080/00958970600990606
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Synthesis and characterization of seven ruthenium(II) and ruthenium(III) complexes of sulphoxide with 2-aminobenzimidazole are reported. Three different formulations exist; [cis-RuCl2(SO)(3)(2-ABZ)]; [trans-RuCl2(SO)(3))(2-ABZ)]; and [trans-RuCl4(SO)(2-ABZ (where SO dimethylsulphoxide(DMSO)/tetramethylenesulphoxide(TMSO); 2-ABZ 2-aminobenzimidazole). These complexes are characterized by elemental analysis, conductivity magnetic susceptibility, H-1-NMR, C-13{H-1}-NMR and electronic spectroscopy.
引用
收藏
页码：1047 / 1055
页数：9
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