Synthesis of novel lactam ionophores containing crown ether moieties and investigation of their extraction abilities towards heavy metal cations

被引：1

作者：

Ertul, Seref ^{[1
]}

机构：

[1] Selcuk Univ, Dept Chem, Fac Sci, TR-42031 Konya, Turkey

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2010年 / 68卷 / 1-2期

关键词：

Crown ether; Lactam; Heavy metal; Liquid-liquid extraction; DICHROMATE ANION; MEMBRANE SELECTIVITY; MACROCYCLIC LACTONES; BINDING-PROPERTIES; DERIVATIVES; POLYETHERS; RECEPTORS; COMPLEXES; DINITRILE; DIAMIDES;

D O I：

10.1007/s10847-010-9736-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The article describes the syntheses and extraction properties of new lactam ionophores. These lactam derivatives were easily synthesized via aminolysis of dimethyl 2,2'-(6,6'-methylenebis(2-tert-butyl-4-methyl-6,1-phenylene)bis(oxy))diacetate or dimethyl 2,2'-(2,2'-methylenebis(4-chloro-2,1-phenylene))bis(oxy)diacetate with corresponding diamine compounds at one step. The extraction studies of lactam ionophores were performed toward dichromate anion and alkaline and transition metals such as Li+, Na+, K+, Co2+, Hg2+ and Pb2+. All the structures of the ionophores were confirmed by spectroscopic techniques and elemental analysis.

引用

页码：85 / 91

页数：7

共 31 条

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