Recent Trends on the Dehydrogenation Catalysis of Liquid Organic Hydrogen Carrier (LOHC): A Review

被引：125
|
作者：
Sekine, Yasushi [1 ]
Higo, Takuma [1 ]
机构：
[1] Waseda Univ, Appl Chem, Shinjuku Ku, 3-4-1 Okubo, Tokyo 1698555, Japan
来源：
TOPICS IN CATALYSIS | 2021年 / 64卷 / 7-8期
关键词：
Dehydrogenation; Reaction mechanism; Liquid organic hydrogen carrier; Methylcyclohexane; Stability; DODECAHYDRO-N-ETHYLCARBAZOLE; METHYLCYCLOHEXANE DEHYDROGENATION; MEMBRANE REACTOR; PERHYDRO-DIBENZYLTOLUENE; KINETICS; RELEASE; STORAGE; PD; SELECTIVITY; GENERATION;
D O I：
10.1007/s11244-021-01452-x
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Considering the expansion of the use of renewable energy in the future, the technology to store and transport hydrogen will be important. Hydrogen is gaseous at an ambient condition, diffuses easily, and its energy density is low. So liquid organic hydrogen carriers (LOHCs) have been proposed as a way to store hydrogen in high density. LOHC can store, transport, and use hydrogen at high density by hydrogenation and dehydrogenation cycles. In this review, we will focus on typical LOHCs, methylcyclohexane (MCH), 18H-dibenzyltoluene (DBT), and 12H-N-ethylcarbazole (NECZ), and summarize recent developments in dehydrogenation catalytic processes, which are key in this cycle.
引用
收藏
页码：470 / 480
页数：11
相关论文
共 50 条
  • [41] Benzyltoluene/perhydro benzyltoluene - pushing the performance limits of pure hydrocarbon liquid organic hydrogen carrier (LOHC) systems
    Ruede, Timo
    Duerr, Stefan
    Preuster, Patrick
    Wolf, Moritz
    Wasserscheid, Peter
    SUSTAINABLE ENERGY & FUELS, 2022, 6 (06) : 1541 - 1553
  • [42] Connected evaluation of polymer electrolyte membrane fuel cell with dehydrogenation reactor of liquid organic hydrogen carrier
    Lee, Sanghun
    Han, Gwangwoo
    Kim, Taehong
    Yoo, Young-Sung
    Jeon, Sang-Yun
    Bae, Joongmyeon
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2020, 45 (24) : 13398 - 13405
  • [43] Roles of bridge carbon and heteroatom during the dehydrogenation reaction of dicyclohexylmethane derivatives on Pd and Pt catalysts for liquid organic hydrogen carrier
    Yook, Hyunwoo
    Jeong, Kwanyong
    Hwang, Jinwoo
    Park, Ji Hoon
    Han, Jeong Woo
    APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2024, 342
  • [44] Microwave enhanced hydrogen production from liquid organic hydrogen carriers: A review
    Sun, Jianchen
    Shang, Hui
    Miao, Chao
    Yang, Jie
    Liao, Yifei
    CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2023, 190
  • [45] Hydrogenation of N-propylcarbazole over supported ruthenium as a new prototype of liquid organic hydrogen carriers (LOHC)
    Yang, Ming
    Dong, Yuan
    Fei, Shunxin
    Pan, Qiyun
    Ni, Gang
    Han, Chaoqun
    Ke, Hanzhong
    Fang, Qiang
    Cheng, Hansong
    RSC ADVANCES, 2013, 3 (47): : 24877 - 24881
  • [46] Parametric study of the hydrogenation of dibenzyltoluene and its dehydrogenation performance as a liquid organic hydrogen carrier
    Ahsan Ali
    Udaya Kumar G
    Hee Joon Lee
    Journal of Mechanical Science and Technology, 2020, 34 : 3069 - 3077
  • [47] Preparation and catalytic performance of dehydrogenation catalyst in organic liquid phase hydrogen storage carrier
    Zhao, Shidong
    Zhou, Luyang
    Shang, Hongyan
    Xu, Yongqiang
    Zhang, Hongwei
    Lin, Xufeng
    Zhongguo Shiyou Daxue Xuebao (Ziran Kexue Ban)/Journal of China University of Petroleum (Edition of Natural Science), 2024, 48 (04): : 215 - 223
  • [48] Catalytic hydrogenation and dehydrogenation performance of 9-ethylcarbazole as a liquid organic hydrogen carrier
    Ahsan Ali
    Udaya Kumar G
    Hee Joon Lee
    Journal of Mechanical Science and Technology, 2019, 33 : 5561 - 5569
  • [49] 7-ethylindole: A new efficient liquid organic hydrogen carrier with fast kinetics
    Chen, Zhiwen
    Yang, Ming
    Zhu, Ting
    Zhang, Zhenlin
    Chen, Xuedi
    Liu, Zhenjie
    Dong, Yuan
    Cheng, Guoe
    Cheng, Hansong
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2018, 43 (28) : 12688 - 12696
  • [50] Si, P, S and Se surface additives as catalytic activity boosters for dehydrogenation of methylcyclohexane to toluene - A liquid organic hydrogen carrier system: Density functional theory insights
    Ouma, Cecil N. M.
    Obodo, Kingsley O.
    Modisha, Phillimon M.
    Bessarabov, Dmitri
    MATERIALS CHEMISTRY AND PHYSICS, 2022, 279
12345