Poly(2-oxazoline)s as Smart Bioinspired Polymers

被引：268

作者：

Schlaad, Helmut ^{[1
]}

Diehl, Christina ^{[1
]}

Gress, Anja ^{[1
]}

Meyer, Matthias ^{[1
]}

Demirel, A. Levent ^{[1
]}

Nur, Yusuf ^{[1
]}

Bertin, Annabelle ^{[1
]}

机构：

[1] Max Planck Inst Colloids & Interfaces, Colloid Dept, D-14424 Potsdam, Germany

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2010年 / 31卷 / 06期

关键词：

biohybrids; macromolecular engineering; polyoxazoline; self-assembly; stimuli-sensitive polymers; RING-OPENING POLYMERIZATION; CRITICAL SOLUTION TEMPERATURE; CYCLIC IMINO ETHERS; TERMINAL FUNCTIONALIZED POLY(N-PROPIONYLETHYLENIMINE)S; TELECHELIC ANTIMICROBIAL FUNCTIONS; METALLO-SUPRAMOLECULAR INITIATORS; PENDANT CARBAZOLE DERIVATIVES; MICROWAVE-ASSISTED SYNTHESIS; STAR-SHAPED POLYOXAZOLINES; ONE-POT SYNTHESIS;

D O I：

10.1002/marc.200900683

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(2-alkyl-2-oxazoline)s can be regarded as pseudo-peptides or bioinspired polymers, which are available through living/controlled cationic polymerization and polymer ("click") modification procedures. Materials and solution properties may be adjusted via the nature of the side chain (hydrophilic-hydrophobic, chiral, bio-functional, etc.), opening the way to stimulus-responsive materials and complex colloidal structures in aqueous environments. Herein, we give an overview over the macromolecular engineering of polyoxazolines, including the synthesis of biohybrids, and the "smart"/bioinspired aggregation behavior in solution.

引用

页码：511 / 525

页数：15

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