Isolation and characterization of [5,6]-pyrrolidino-Sc3N@Ih-C80 diastereomers

被引：14
|
作者：
Maeda, Yutaka [1 ]
Kimura, Masato [2 ]
Ueda, Chihiro [1 ]
Yamada, Michio [1 ]
Kikuchi, Toru [1 ]
Suzuki, Mitsuaki [1 ]
Wang, Wei-Wei [3 ]
Mizorogi, Naomi [2 ]
Karousis, Nikolaos [4 ]
Tagmatarchis, Nikos [4 ]
Hasegawa, Tadashi [1 ]
Olmstead, Marilyn M. [5 ]
Balch, Alan L. [5 ]
Nagase, Shigeru [3 ]
Akasaka, Takeshi [1 ,2 ,6 ,7 ]
机构：
[1] Tokyo Gakugei Univ, Dept Chem, Koganei, Tokyo 1848501, Japan
[2] Univ Tsukuba, Life Sci Ctr, Tsukuba Adv Res Alliance, Tsukuba, Ibaraki 3058577, Japan
[3] Kyoto Univ, Fukui Inst Fundamental Chem, Kyoto 6068103, Japan
[4] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece
[5] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
[6] Huazhong Univ Sci & Technol, Coll Mat Sci & Engn, Wuhan 430074, Peoples R China
[7] Fdn Advancement Int Sci, Tsukuba, Ibaraki 3050821, Japan
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 83期
基金：
美国国家科学基金会;
关键词：
ENDOHEDRAL METALLOFULLERENES; ELECTROCHEMICAL PROPERTIES; THERMOCHEMICAL KINETICS; DENSITY FUNCTIONALS; M3N-AT-C-80; M; REACTIVITY; I-H-SC3N-AT-C-80; CYCLOADDITION; SC3N-AT-C-80; DERIVATIVES;
D O I：
10.1039/c4cc04946b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactions of Sc3N@I-h-C-80 with aziridine derivatives were conducted to afford the corresponding mono-adducts. A pair of diastereomers of the mono-adduct [5,6]-pyrrolidino-Sc3N@I-h-C-80 was isolated and characterized by means of mass spectrometry, vis-NIR absorption spectroscopy, and electrochemical measurements. Structural analysis of the mono-adducts was conducted by NMR and single-crystal X-ray structure determinations.
引用
收藏
页码：12552 / 12555
页数：4
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