Limonene as a renewable unsaturated hydrocarbon solvent for living anionic polymerization of β-myrcene

被引：17

作者：

Dev, Akhil ^{[1
]}

Roesler, Alexander ^{[1
]}

Schlaad, Helmut ^{[1
]}

机构：

[1] Univ Potsdam, Inst Chem, Karl Liebknecht Str 24-25, D-14476 Potsdam, Germany

来源：

POLYMER CHEMISTRY | 2021年 / 12卷 / 21期

关键词：

CONTROLLED RADICAL POLYMERIZATION; COPOLYMERIZATION; ELASTOMERS; POLYMYRCENE; ISOPRENE;

D O I：

10.1039/d1py00570g

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The acyclic monoterpene beta-myrcene is polymerized by anionic polymerization at room temperature using sec-butyllithium as the initiator and the cyclic monoterpene DL-limonene as an unsaturated hydrocarbon solvent. The polymerization is a living process and allows production of polymyrcenes with narrow molar mass distribution ((sic) similar to 1.06) and high content of 1,4 units (similar to 90%) as well as block copolymers.

引用

页码：3084 / 3087

页数：4

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