Production of C4 and C5 alcohols from biomass-derived materials

被引：168

作者：

Sun, Daolai ^{[1
]}

Sato, Satoshi ^{[1
]}

Ueda, Wataru ^{[2
]}

Primo, Ana ^{[3
]}

Garcia, Hermenegildo ^{[3
]}

Corma, Avelino ^{[3
]}

机构：

[1] Chiba Univ, Grad Sch Engn, Chiba 2638522, Japan

[2] Univ Politecn Valencia, Inst Chem Technol, Av Naranjos S-N, Valencia 46022, Spain

[3] Kanagawa Univ, Engn Dept Mat & Life Chem, Kanagawa, Japan

来源：

GREEN CHEMISTRY | 2016年 / 18卷 / 09期

关键词：

AQUEOUS-PHASE HYDROGENATION; SUPPORTED BIMETALLIC CATALYSTS; HIGHLY SELECTIVE HYDROGENATION; CONTAINING MESOPOROUS CARBON; AMORPHOUS ALLOY CATALYSTS; FURFURYL ALCOHOL; SUCCINIC ACID; LIQUID-PHASE; LEVULINIC ACID; TETRAHYDROFURFURYL ALCOHOL;

D O I：

10.1039/c6gc00377j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C4 and C5 diols and alcohols are important commodity chemicals mainly used as monomers in the production of polyesters, polyurethanes and polyethers. C4 and C5, on the other hand, can be used in the fuel industry for the preparation of additives to boost the gasoline octane number. The present critical review covers those reports describing the obtainment of these diols and alcohols from precursors derived from biomass. Emphasis is made on the description of the catalysts required for these transformations and on common traits referring to the bifunctionality combining hydrogenation activity and acidity and on the mechanistic proposals. The need for finding a suitable replacement for noble metals on the composition of these catalysts has been remarked throughout the review.

引用

页码：2579 / 2597

页数：19

共 109 条

[1]

Aldo B., 1999, United States Pat, Patent No. [US1999/9935114, 19999935114]

[2] Selective Hydrogenation of Furfural to Furfuryl Alcohol in the Presence of a Recyclable Cobalt/SBA-15 Catalyst [J].