Honeycomb-like 2D metal-organic polyhedral framework exhibiting selectively adsorption of CO2

被引：7
作者：
Du, Liting [1 ,3 ]
Miao, Yinchun [3 ]
Zheng, Baishu [2 ]
Ma, Mengtao [4 ]
Zhang, Jinchi [1 ]
机构：
[1] Nanjing Forestry Univ, Collaborat Innovat Ctr Sustainable Forestry South, 159 Longpan Rd, Nanjing 210037, Jiangsu, Peoples R China
[2] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Hunan Prov Key Lab Controllable Preparat & Funct, Key Lab Theoret Organ Chem & Funct Mol,Minist Edu, Xiangtan 411201, Peoples R China
[3] Nanjing Forestry Univ, Adv Anal & Testing Ctr, Nanjing 210037, Peoples R China
[4] Nanjing Forestry Univ, Coll Sci, Nanjing 210098, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2021年 / 300卷
基金：
中国国家自然科学基金;
关键词：
Metal-organic polyhedral framework; Honeycomb-net; Noncovalent interactions; Gas adsorption and separation; COORDINATION POLYMERS; ENERGY-TRANSFER; CONVERSION; CAPTURE; MOFS;
D O I：
10.1016/j.jssc.2021.122230
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new honeycomb-like 2D Metal-organic polyhedral framework, {Cu-3.75(BrCPEIP)(2.5)center dot(H2O)(2.75)center dot DMF}(n) (NJFU-5, H3BrCPEIP = 5-((3-bromo-5-carboxyphenyl)ethynyl)isophthalic acid) was solvothermally synthesized and structurally characterized, which shows a BET surface area of 473 m(2) g(-1). Meanwhile, NJFU exhibits a comparably higher CO2 adsorption capacity of 37.0 cm(3) g(-1) (4.6 wt%) at 1 bar and 298 K in 2D MOF family, and a high CO2 selective adsorption toward N-2 and CH4 as well.
引用
收藏
页数：4
相关论文
共 51 条
[1]   Small gas molecules access into void space of H-bonded 3D network consist of 2D cadmium(II) layer [J].
Biswas, Saptarshi ;
Gayen, Saikat ;
Maity, Tanmoy ;
Koner, Subratanath .
INORGANICA CHIMICA ACTA, 2017, 461 :21-26
[2]   Orthogonal self-assembly of a trigonal triptycene triacid: signaling of exfoliation of porous 2D metal-organic layers by fluorescence and selective CO2 capture by the hydrogen-bonded MOF [J].
Chandrasekhar, Pujari ;
Mukhopadhyay, Arindam ;
Savitha, Govardhan ;
Moorthy, Jarugu Narasimha .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (11) :5402-5412
[3]   One-dimensional La(III) coordination polymer displaying multi-responsive luminescence activities towards Fe3+, acetone and benzothiozoles [J].
Chen, Yuqian ;
Xian, Guoxuan ;
Yan, Hui ;
Wang, Yuhao ;
Li, Yunwu ;
Lu, Jing ;
Xu, Haijun ;
Tao, Jiayu ;
Wang, Suna .
JOURNAL OF SOLID STATE CHEMISTRY, 2021, 296 (296)
[4]   Temperature-Dependent Morphologies of Precursors: Metal-Organic Framework-Derived Porous Carbon for High-Performance Electrochemical Double-Layer Capacitors [J].
Duan, Hui-Hui ;
Bai, Cai-He ;
Li, Jia-Yi ;
Yang, Ying ;
Yang, Bo-Long ;
Gou, Xiao-Feng ;
Yue, Man-Li ;
Li, Zuo-Xi .
INORGANIC CHEMISTRY, 2019, 58 (04) :2856-2864
[5]   Metal-organic framework nanosheets: An emerging family of multifunctional 2D materials [J].
Duan, Jingui ;
Li, Yanshuo ;
Pan, Yichang ;
Behera, Nibedita ;
Jin, Wanqin .
COORDINATION CHEMISTRY REVIEWS, 2019, 395 :25-45
[6]  
Farha OK, 2010, NAT CHEM, V2, P944, DOI [10.1038/nchem.834, 10.1038/NCHEM.834]
[7]   A supermolecular building approach for the design and construction of metal-organic frameworks [J].
Guillerm, Vincent ;
Kim, Dongwook ;
Eubank, Jarrod F. ;
Luebke, Ryan ;
Liu, Xinfang ;
Adil, Karim ;
Lah, Myoung Soo ;
Eddaoudi, Mohamed .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :6141-6172
[8]   CO2 Capture in Metal-Organic Framework Adsorbents: An Engineering Perspective [J].
Hu, Zhigang ;
Wang, Yuxiang ;
Shah, Bhuvan B. ;
Zhao, Dan .
ADVANCED SUSTAINABLE SYSTEMS, 2019, 3 (01)
[9]   A Triphasic Modulated Hydrothermal Approach for the Synthesis of Multivariate Metal-Organic Frameworks with Hydrophobic Moieties for Highly Efficient Moisture-Resistant CO2 Capture [J].
Hu, Zhigang ;
Gami, Abhishek ;
Wang, Yuxiang ;
Zhao, Dan .
ADVANCED SUSTAINABLE SYSTEMS, 2017, 1 (11)
[10]   Ionized Zr-MOFs for highly efficient post-combustion CO2 capture [J].
Hu, Zhigang ;
Khurana, Maninder ;
Seah, Yong Huang ;
Zhang, Mei ;
Guo, Zhengang ;
Zhao, Dan .
CHEMICAL ENGINEERING SCIENCE, 2015, 124 :61-69
123456