Free-radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes

被引：7
|
作者：
Tian, Yunfei [1 ]
Ling, Anbo [2 ]
Fang, Ren [2 ]
Tan, Ren Xiang [1 ]
Liu, Zhong-Quan [1 ,2 ]
机构：
[1] Nanjing Univ Chinese Med, Coll Pharm, State Key Lab Cultivat Base TCM Qual & Efficacy, Nanjing 210023, Jiangsu, Peoples R China
[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
来源：
GREEN CHEMISTRY | 2018年 / 20卷 / 15期
基金：
中国国家自然科学基金;
关键词：
C-H BONDS; CATALYZED DECARBOXYLATIVE ALKENYLATION; C(SP(3))-H BOND; OXIDATIVE FUNCTIONALIZATION; FLUORINATED ALCOHOLS; CINNAMIC-ACIDS; ALKYL IODIDES; HETEROCYCLES; ACTIVATION; CYCLOALKANES;
D O I：
10.1039/c8gc01394b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Cu(II)-mediated radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes via selective C(sp(3))-H bond cleavage was achieved. This reaction features high site-selectivity diverse functional group tolerance, and scalability.
引用
收藏
页码：3432 / 3435
页数：4
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