Nickel-catalyzed (hetero)aryl borylations: an update

被引：6

作者：

Mole, Julie ^{[1
]}

Philip, Rose Mary ^{[1
]}

Anilkumar, Gopinathan ^{[1
]}

机构：

[1] Mahatma Gandhi Univ, Sch Chem Sci, Kottayam 686560, Kerala, India

来源：

ARKIVOC | 2022年

关键词：

Organoboron compounds; borylation; Ni catalysts; aryl borylation; Hetero aryl borylation; CROSS-COUPLING REACTION; ARYL HALIDES; SYNTHETIC ROUTE; NEOPENTYLGLYCOLBORYLATION; FUNCTIONALIZATION; ARENES; BIS(PINACOLATO)DIBORON; DIALKOXYBORANE; SILYLATION; MESYLATES;

D O I：

10.24820/ark.5550190.p011.707

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aromatic organoboron compounds serve as important intermediates in synthetic organic chemistry. While the traditional electrophilic borylations using aromatic lithium or magnesium reagents had several limitations, transition metal catalyzed borylations emerged as a promising method. In recent years, borylation reactions catalyzed by Ni have gained great attention due to its enormous importance as a cheaper and less toxic alternative to Pd catalysts. The present review focuses on the recent developments in the arena of Ni catalyzed (hetero)aryl borylations after 2013.

引用

页码：165 / 199

页数：35

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