Wacker reaction in supercritical carbon dioxide

被引：73

作者：

Jiang, HF ^{[1
]}

Jia, LQ ^{[1
]}

Li, JH ^{[1
]}

机构：

[1] Chinese Acad Sci, Guangzhou Inst Chem, LCLC, Guangzhou 510650, Peoples R China

来源：

GREEN CHEMISTRY | 2000年 / 2卷 / 04期

关键词：

D O I：

10.1039/b002491k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It is reported for the first time that the Wacker reaction can be carried out smoothly in supercritical carbon dioxide or ROH/supercritical carbon dioxide. Results show that both scCO(2) and co-solvent can remarkably affect the selectivity towards methyl ketone and the presence of ROH accelerates the reaction. The mechanism of the Wacker reaction in scCO(2) is also discussed.

引用

页码：161 / 164

页数：4

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