Hydrosilylation of ketones catalyzed by novel four-coordinate copper(I) complexes under mild conditions

被引：7
作者：
Li, Zhi-Wen [1 ]
An, Dong-Li [1 ]
Wei, Zan-Bin [1 ]
Li, Yan-Yun [1 ]
Gao, Jing-Xing [1 ]
机构：
[1] Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Peoples R China
来源：
TETRAHEDRON LETTERS | 2022年 / 97卷
关键词：
Copper(I) complex; P x N y -type ligand; Non-precious metal catalyst; Hydrosilylation; Ketone; ASYMMETRIC TRANSFER HYDROGENATION; HIGHLY ENANTIOSELECTIVE REDUCTION; AROMATIC KETONES; COPPER(II)-DIPYRIDYLPHOSPHINE CATALYST; IRON; CUH; LIGANDS; COBALT; P; N-LIGANDS; VERSATILE;
D O I：
10.1016/j.tetlet.2022.153798
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Using conveniently available Cu(CH3CN)4PF6 and PxNy-type ligands as starting material, copper(I) complexes 1 and 2 could be easily prepared. Furtherly, we confirmed the structures of these novel copper (I) complexes by studying X-ray diffraction of the single crystals. The hydrosilylation of a wide range of ketones catalyzed by the well-designed copper(I) complex proceeded smoothly under mild reaction conditions, obtaining the corresponding alcohols with high yields. (c) 2022 Elsevier Ltd. All rights reserved.
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页数：6
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共 63 条
  • [1] Chemo- and Stereoselective Iron-Catalyzed Hydrosilylation of Ketones
    Addis, Daniele
    Shaikh, Nadim
    Zhou, Shaolin
    Das, Shoubhik
    Junge, Kathrin
    Beller, Matthius
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2010, 5 (07) : 1687 - 1691
  • [2] First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands
    Alig, Lukas
    Fritz, Maximilian
    Schneider, Sven
    [J]. CHEMICAL REVIEWS, 2019, 119 (04) : 2681 - 2751
  • [3] Bis(oxazoline)titanium complexes as chiral catalysts for enantioselective hydrosilylation of ketones - A combined experimental and theoretical investigation
    Bandini, M
    Bernardi, F
    Bottoni, A
    Cozzi, PG
    Miscione, GP
    Umani-Ronchi, A
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 2003 (15) : 2972 - 2984
  • [4] Berger R.G, 2007, FLAVOURS FRAGRANCES
  • [5] [Zinc-diamine]-catalyzed hydrosilylation of ketones in methanol. New developments and mechanistic insights
    Bette, V
    Mortreux, A
    Savoia, D
    Carpentier, JF
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2005, 347 (2-3) : 289 - 302
  • [6] Chiral P,N-ligands with pyridine-nitrogen and phosphorus donor atoms.: Syntheses and applications in asymmetric catalysis
    Chelucci, G
    Orrù, G
    Pinna, GA
    [J]. TETRAHEDRON, 2003, 59 (48) : 9471 - 9515
  • [7] Asymmetric transfer hydrogenation of aromatic ketones catalyzed by the iridium hydride complex under ambient conditions
    Chen, JS
    Li, YY
    Dong, ZR
    Li, BZ
    Gao, JX
    [J]. TETRAHEDRON LETTERS, 2004, 45 (45) : 8415 - 8418
  • [8] CuH-catalyzed reactions
    Deutsch, Carl
    Krause, Norbert
    Lipshutz, Bruce H.
    [J]. CHEMICAL REVIEWS, 2008, 108 (08) : 2916 - 2927
  • [9] Cationic copper(I) complexes as efficient precatalysts for the hydrosilylation of carbonyl compounds
    Díez-González, S
    Scott, NM
    Nolan, SP
    [J]. ORGANOMETALLICS, 2006, 25 (09) : 2355 - 2358
  • [10] A simple and efficient copper-catalyzed procedure for the hydrosilylation of hindered and functionalized ketones
    Díez-González, S
    Kaur, H
    Zinn, FK
    Stevens, ED
    Nolan, SP
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (12) : 4784 - 4796
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