Effect of annealing treatment on the structure and properties of the nanograined TiN coatings produced by ultrasonic-based coating process

被引:6
作者
Romankov, S. [1 ]
Hayasaka, Y. [2 ]
Hayashi, N. [1 ]
Kasai, E. [1 ]
Komarov, S. [3 ]
机构
[1] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan
[2] Tohoku Univ, High Electron Voltage Microscope Lab, Sendai, Miyagi 9808577, Japan
[3] Nippon Light Met Co Ltd, NRDC, Shizuoka 4213291, Japan
关键词
Coating materials; Nanostructured materials; Nitride materials; Mechanical alloying; MECHANICAL ATTRITION TREATMENT; SURFACE-LAYER; EVOLUTION;
D O I
10.1016/j.jallcom.2009.10.170
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An ultrasonic mechanical coating and armouring (UMCA) process was used for the deposition of the nanograined TIN coatings During the UMCA process, the substrate surface was subjected to high-energy ball impacts The repeated substrate-to-ball collisions made the precoated TIN particles cold weld to each other and to the substrate The UMCA method allows nanograined TiN coatings to be produced on different substrates in a short time at room temperature in an ambient atmosphere Under the applied compressive loading, the substrate became strongly deformed. The gram refinement occurred and many randomly orientated nanosized grains developed near the substrate surface Annealing treatment in temperatures ranging between 200 degrees C and 600 degrees C improved adhesion of the coatings and Increased hardness The nanoparticles had a tendency to consolidate with increasing annealing temperature The growth of crystallites started at 400 degrees C After annealing at 600 degrees C, a solid state reaction between Al and TiN leads to the formation of a new phase that could be intermetallic compound AlTi(3). (C) 2009 Elsevier B V All rights reserved
引用
收藏
页码:625 / 628
页数:4
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