Synthesis and Optical Properties of Europium-Complex-Doped Inorganic/Organic Hybrid Materials Built from Oxo-Hydroxo Organotin Nano Building Blocks

被引：62
作者：
Fan, Wei-Qiang [1 ,2 ]
Feng, Jing [1 ,2 ]
Song, Shu-Yan [1 ,2 ]
Lei, Yong-Qian [1 ,2 ]
Zheng, Guo-Li [1 ,2 ]
Zhang, Hong-Jie [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 06期
基金：
中国国家自然科学基金;
关键词：
europium; hybrid materials; luminescence; nanostructures; organotin; LUMINESCENCE PROPERTIES; NANOBUILDING BLOCKS; SILICA; COPOLYMERS; EU3+; HYDROLYSIS; POLYMERS; BEHAVIOR; ACID; LN;
D O I：
10.1002/chem.200902111
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hybrid materials doped with novel europium complexes were synthesized using PMMA-co-Sn(12)Clusters (copolymers from oxohydroxo-organotin dimethacrylate and methylmethacrylate) as the matrix material. Two types of hybrid materials were obtained: the physically doped product, PMMA-co-Sn(12)Cluster/Eu(TTA)(3)phen, and the grafted product, PMMA-co-Sn(12)Cluster-co-[EuAA(TTA)(2)phen] (TTA =2-thenoyltrifluoroacetone, phen=phenanthroline and AA=acrylic acid). The hybrid materials exhibited characteristic luminescence of the Eu3+ ions, and also showed relative especial optical properties compared with samples just using PMMA as the matrix material. The PMMA-co-Sn(12)Cluster matrix exhibited a high physical doping quantity of [Eu(TTA)(3)phen], which can be attributed to the special structure of this kind of hybrid material. GPC (gel-permeation chromatography), TGA (thermogravimetric analysis), SEM, H-1 NMR, ICP (inductively coupled plasma), Sn-119 NMR. FTIR. and diffuse reflectance techniques were employed to characterize the structures and properties of these hybrid materials.
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收藏
页码：1903 / 1910
页数：8
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