Solubility of anthracene in ternary 1,4-dioxane plus alcohol plus heptane solvent mixtures at 298.15 K

被引：9
作者：
Pribyla, KJ [1 ]
Spurgin, MA [1 ]
Chuca, I [1 ]
Acree, WE [1 ]
机构：
[1] Univ N Texas, Dept Chem, Denton, TX 76203 USA
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2000年 / 45卷 / 05期
关键词：
D O I：
10.1021/je0001173
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Experimental solubilities are reported for anthracene dissolved in ternary 1,4-dioxane + 1-propanol + heptane, 1,4-dioxane + 2-propanol + heptane, 1,4-dioxane + 2-butanol + heptane, 1,4-dioxane + 2-butanol + heptane, and 1,4-dioxane + 2-methyl-1-propanol + heptane solvent mixtures at 25 degrees C and atmospheric pressure. Nineteen compositions were studied for each of the five solvent systems. Results of these measurements are used to test the predictive ability of the ternary solvent form of the combined NIMS/Redlich-Kister equation. Computations showed that the model predicted the observed solubility behavior to within an overall average absolute deviation of about 3.7%.
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页码：965 / 967
页数：3
相关论文
共 21 条
[1]   MATHEMATICAL REPRESENTATION OF THERMODYNAMIC PROPERTIES - CARBAZOLE SOLUBILITIES IN BINARY ALKANE + DIBUTYL ETHER AND ALKANE + TETRAHYDROPYRAN SOLVENT MIXTURES [J].
ACREE, WE ;
MCCARGAR, JW ;
ZVAIGZNE, AI ;
TENG, IL .
PHYSICS AND CHEMISTRY OF LIQUIDS, 1991, 23 (01) :27-35
[2]   MATHEMATICAL REPRESENTATION OF THERMODYNAMIC PROPERTIES .2. DERIVATION OF THE COMBINED NEARLY IDEAL BINARY SOLVENT (NIBS) REDLICH-KISTER MATHEMATICAL REPRESENTATION FROM A 2-BODY AND 3-BODY INTERACTIONAL MIXING MODEL [J].
ACREE, WE .
THERMOCHIMICA ACTA, 1992, 198 (01) :71-79
[3]   THERMODYNAMIC PROPERTIES OF NONELECTROLYTE SOLUTIONS .4. ESTIMATION AND MATHEMATICAL REPRESENTATION OF SOLUTE ACTIVITY-COEFFICIENTS AND SOLUBILITIES IN BINARY SOLVENTS USING THE NIBS AND MODIFIED WILSON EQUATIONS [J].
ACREE, WE ;
ZVAIGZNE, AI .
THERMOCHIMICA ACTA, 1991, 178 :151-167
[4]   THERMOCHEMICAL INVESTIGATIONS OF HYDROGEN-BONDED SOLUTIONS - DEVELOPMENT OF A PREDICTIVE EQUATION FOR THE SOLUBILITY OF ANTHRACENE IN BINARY HYDROCARBON PLUS ALCOHOL MIXTURES BASED UPON MOBILE ORDER THEORY [J].
ACREE, WE ;
ZVAIGZNE, AI ;
TUCKER, SA .
FLUID PHASE EQUILIBRIA, 1994, 92 :233-253
[5]  
ACREE WE, 1994, IUPAC SOLUBILITY DAT, V54
[6]  
ACREE WE, 1995, IUPAC SOLUBILITY DAT, V58
[7]  
ACREE WE, 1995, IUPAC SOLUBILITY DAT, V59
[8]   Solubility of anthracene in ternary propanol plus butanol plus heptane solvent mixtures [J].
Deng, TH ;
Childress, SD ;
De Fina, KM ;
Acree, WE .
CHEMICAL ENGINEERING COMMUNICATIONS, 1999, 172 :217-224
[9]   Solubility of anthracene in ternary propanol plus butanol plus 2,2,4-trimethylpentane solvent mixtures [J].
Deng, TH ;
Childress, SD ;
De Fina, KM ;
Sharp, TL ;
Acree, WE .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1998, 43 (06) :1065-1067
[10]   Solubility of anthracene in ternary (propanol plus heptane plus cyclohexane) and (butanol plus heptane plus cyclohexane) solvent mixtures [J].
Deng, TH ;
Hernández, CE ;
Roy, LE ;
Acree, WE .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1999, 31 (02) :205-210
123