A versatile logic detector and fluorescent film based on Eu-based MOF for swift detection of formaldehyde in solutions and gas phase

被引:46
作者
Che, Huachao [1 ]
Li, Yong [1 ]
Tian, Xike [1 ]
Yang, Chao [1 ]
Lu, Liqiang [1 ]
Nie, Yulun [1 ]
机构
[1] China Univ Geosci, Fac Mat Sci & Chem, Wuhan 430074, Peoples R China
基金
中国国家自然科学基金;
关键词
Eu-based MOF; Logic detector; Fluorescent film; Formaldehyde; Fluorescence detection;
D O I
10.1016/j.jhazmat.2020.124624
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Due to the huge threat of formaldehyde (FA) on human beings, the development of chemical sensors for swift detection of FA in solutions and gas phase is highly anticipated. In this paper, a versatile logic detector and a portable fluorescent film based on small-scaled Eu-based MOF were applied successfully to detect FA in solutions and gas phase, respectively. For FA in aqueous solution, the design of logic detector will efficiently identify FA in different concentration ranges: when the FA concentration are 0?500 ppb, 500?1000 ppb and >1000 ppb, the output signals of logic detector are the concentration level of FA ("L", "H" and "VH"), and accompanied by red, purple and blue signal lamps to remind, respectively. For FA in the air, the color of rigid film sensor will gradually change from red to blue with the increase of FA under UV lamp, and the detection limit of gaseous FA is 11.8 ppb. Through the preparation of logic devices and fluorescent films, Eu-based MOF realized swift detection of FA in solutions and gas phase, which will be very helpful to improve the human response level to FA from different emission sources.
引用
收藏
页数:10
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