Recent advances in the catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides

被引：335

作者：

Adrio, Javier ^{[1
]}

Carretero, Juan C. ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Fac Ciencias, Dept Quim Organ, E-28049 Madrid, Spain

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 83期

关键词：

ENANTIOSELECTIVE 3+2 CYCLOADDITION; DIELS-ALDER REACTIONS; X=Y-ZH COMPOUNDS; ONE-POT; PYRROLIDINE DERIVATIVES; EFFICIENT CONSTRUCTION; POTENTIAL 1,3-DIPOLES; CHIRAL CATALYSTS; FACILE ACCESS; AMINO ESTERS;

D O I：

10.1039/c4cc04381b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic asymmetric 1,3-dipolar cycloadditions of azomethine ylides have turned out to be one of the most efficient methods for the preparation of enantioenriched pyrrolidines. The past decade has witnessed the development of a bunch of well-defined catalytic systems capable of affording excellent diastereo and enantioselectivities. Recently, a great effort has been focused on expanding the scope of the cycloaddition with regard to both reaction partners. In this review, we will discuss important advances that have been reported in this area since 2011.

引用

页码：12434 / 12446

页数：13

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