A high-throughput, controllable, and environmentally benign fabrication process of thermoplastic nanofibers

被引:137
作者
Wang, Dong
Sun, Gang [1 ]
Chiou, Bor-Sen
机构
[1] Univ Calif Davis, Davis, CA 95616 USA
[2] USDA, WRRC, ARS, Albany, CA 94710 USA
关键词
extrusion; immiscible blends; nanocomposites; nanofibers; thermoplastics;
D O I
10.1002/mame.200600460
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Continuous and uniform yarns of thermoplastic nanofibers were prepared via direct melt extrusion of immiscible blends of thermoplastic polymers with CAB and subsequent extraction removal of CAB. Ratios of thermoplastic/sacrificial polymers, melt viscosity, and interfacial tensions affect the formation of nanofibers. Dominating sacrificing polymer content in the blends and low interfacial tensions between thermoplastic polymer and CAB are two key factors. This lity of thermoplastics, controllability, and environment friendliness in manufacturing thermoplastic nanofibers. fabrication process possesses features of high productivity, versati-
引用
收藏
页码:407 / 414
页数:8
相关论文
共 18 条
[1]   Direct in vitro electrospinning with polymer melts [J].
Dalton, PD ;
Klinkhammer, K ;
Salber, J ;
Klee, D ;
Möller, M .
BIOMACROMOLECULES, 2006, 7 (03) :686-690
[2]   Electrospinning of polymer nanofibers with specific surface chemistry [J].
Deitzel, JM ;
Kosik, W ;
McKnight, SH ;
Tan, NCB ;
DeSimone, JM ;
Crette, S .
POLYMER, 2002, 43 (03) :1025-1029
[3]   Nanoprocessing of polymers: applications in medicine, sensors, catalysis, photonics [J].
Dersch, R ;
Steinhart, M ;
Boudriot, U ;
Greiner, A ;
Wendorff, JH .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2005, 16 (2-3) :276-282
[4]   Spinning continuous fibers for nanotechnology [J].
Dzenis, Y .
SCIENCE, 2004, 304 (5679) :1917-1919
[5]   A review on polymer nanofibers by electrospinning and their applications in nanocomposites [J].
Huang, ZM ;
Zhang, YZ ;
Kotaki, M ;
Ramakrishna, S .
COMPOSITES SCIENCE AND TECHNOLOGY, 2003, 63 (15) :2223-2253
[6]  
KANNAN M, 2004, SYNTH FIBRES, V33, P11
[7]   THE MANUFACTURE OF CONTINUOUS POLYMERIC FILAMENTS BY THE MELT-BLOWING PROCESS [J].
KAYSER, JC ;
SHAMBAUGH, RL .
POLYMER ENGINEERING AND SCIENCE, 1990, 30 (19) :1237-1251
[8]   STRUCTURE AND FILTRATION PROPERTIES OF MELT BLOWN POLYPROPYLENE WEBS [J].
LEE, YC ;
WADSWORTH, LC .
POLYMER ENGINEERING AND SCIENCE, 1990, 30 (22) :1413-1419
[9]   Melt-electrospinning part I: processing parameters and geometric properties [J].
Lyons, J ;
Li, C ;
Ko, F .
POLYMER, 2004, 45 (22) :7597-7603
[10]  
Mukhopadhyay S, 2002, INDIAN J FIBRE TEXT, V27, P307