Lithium perchlorate diethyl ether solution: A highly efficient media for the Abramov reaction

被引：48

作者：

Azizi, N ^{[1
]}

Saidi, MR ^{[1
]}

机构：

[1] Sharif Univ Technol, Dept Chem, Tehran, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2003年 / 178卷 / 06期

关键词：

Abramov reaction; alpha-hydroxy phosphonates; lithium perchlorate;

D O I：

10.1080/10426500307904

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The alpha-hydroxy phosphonates are readily prepared by treating aromatic or aliphatic aldehydes and ketones with trialkylphosphite in the presence of trimethylsilylchloride in a very short time and in almost quantitative yields.

引用

页码：1255 / 1259

页数：5

共 18 条

[1] A new protocol for the Baylis-Hillman reaction: the reaction of iminium salts prepared in situ with methyl acrylate [J].

Azizi, N ;

Saidi, MR .

TETRAHEDRON LETTERS, 2002, 43 (24) :4305-4308

[2] PHOSPHONATES AS ANALOGS OF NATURAL PHOSPHATES [J].

ENGEL, R .

CHEMICAL REVIEWS, 1977, 77 (03) :349-367

[3] Synthesis of phosphonates by nucleophilic substitution at phosphorus:: The SNP(V) reaction. [J].

Eymery, F ;

Iorga, B ;

Savignac, P .

TETRAHEDRON, 1999, 55 (46) :13109-13150

[4] High yield preparation of a-ketophosphonates by oxidation of α-hydroxyphosphonates with zinc dichromate trihydrate (ZnCr2O7•3H2O) under solvent-free conditions [J].

Firouzabadi, H ;

Iranpoor, N ;

Sobhani, S ;

Sardarian, AR .

TETRAHEDRON LETTERS, 2001, 42 (26) :4369-4371

[5]

Gröger H, 2000, CHEM-EUR J, V6, P943

[6] Controlled monohalogenation of phosphonates:: A new route to pure α-monohalogenated diethyl benzylphosphonates [J].

Iorga, B ;

Eymery, F ;

Savignac, P .

TETRAHEDRON, 1999, 55 (09) :2671-2686

[7] Synthesis of dialkyl-hydroxymethylphosphonates in heterogeneous conditions [J].

Jeanmaire, T ;

Hervaud, Y ;

Boutevin, B .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2002, 177 (05) :1137-1145

[8]

Kumar KP, 2001, TETRAHEDRON LETT, V42, P3219

[9] AT THE CROSSROADS OF CHEMISTRY AND IMMUNOLOGY - CATALYTIC ANTIBODIES [J].

LERNER, RA ;

BENKOVIC, SJ ;

SCHULTZ, PG .

SCIENCE, 1991, 252 (5006) :659-667

[10] THE WITTIG OLEFINATION REACTION AND MODIFICATIONS INVOLVING PHOSPHORYL-STABILIZED CARBANIONS - STEREOCHEMISTRY, MECHANISM, AND SELECTED SYNTHETIC ASPECTS [J].

MARYANOFF, BE ;

REITZ, AB .

CHEMICAL REVIEWS, 1989, 89 (04) :863-927

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