(E)-1-(4-Methylphenyl)ethanone [8-(trifluoromethyl)quinolin-4-yl]hydrazone

被引:7
作者
Dutkiewicz, Grzegorz [1 ]
Mayekar, Anil N. [2 ]
Yathirajan, H. S. [2 ]
Narayana, B. [3 ]
Kubicki, Maciej [1 ]
机构
[1] Adam Mickiewicz Univ, Dept Chem, PL-60780 Poznan, Poland
[2] Univ Mysore, Dept Studies Chem, Mysore 570006, Karnataka, India
[3] Mangalore Univ, Dept Studies Chem, Mangalagangothri 574199, Karnataka, India
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
D O I
10.1107/S1600536810009475
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C19H16F3N3, the dihedral angle between the naphthalene and quinoline ring systems is 14.58 (8)degrees. The hydrazone C-N-N = C-C chain is in an extended conformation and its mean plane is nearly coplanar with the quinoline plane [dihedral angle = 3.45 (9)degrees]. The bond angles within the phenyl ring show the almost additive influence of the two para substituents. In the crystal, weak pi-pi [centroid-centroid distances = 3.779 (2) and 3.718 (1) angstrom] and C-H center dot center dot center dot F directional interactions join the molecules into centrosymmetric dimers, which are further connected into infinite zigzag chains propagating along a.
引用
收藏
页码:O874 / U2684
页数:10
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