Bis{μ-2-[(E)-(3,5-dibromo-2-oxidophenyl)methyleneamino]ethanesulfonato-κ3N,O,O′:κO "}bis[methanolcopper(II)]

被引：6

作者：

Chen, Xian-Ming

Zhang, Shu-Hua ^{[1
]}

Yang, Yan

机构：

[1] Guilin Univ Technol, Dept Chem & Mat Engn, Key Lab Nonferrous Met Mat & Proc Technol, Minist Educ, Guilin 541004, Peoples R China

[2] Yulin Teachers Coll, Yulin 537000, Guangxi, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

single-crystal X-ray study; T=293 K; MEan sigma(C-C)=0.016 angstrom; R factor=0.071; wR factor=0.209; Data-to-parameter ratio=13.6;

D O I：

10.1107/s1600536807015905

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the centrosymmetric title compound, [Cu-2(C9H7Br2-NO4S)(2)(CH3OH)(2)], each Cu-II atom adopts a distorted square-pyramidal CuO4N coordination geometry, formed by one N atom and three O atoms from two different 2-[(E)-(3,5dibromo-2-oxidophenyl)methyleneamino] ethanesulfonate ligands and one O atom from a methanol molecule. Adjacent Cu-II atoms are linked by bridging sulfonate groups to form a dinuclear compound, with a Cu . . . Cu distance of 5.41 (1) angstrom.

引用

页码：M1317 / M1318

页数：2

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