Structural degradation mechanism of multiwalled carbon nanotubes in electrically treated field emission

被引:22
作者
Baik, Chan-Wook [1 ]
Lee, Jeonghee [1 ]
Choi, Jun Hee [1 ]
Jung, Insun [1 ]
Choi, Hye Ran [1 ]
Jin, Yong Wan [1 ]
Kim, Jong Min [1 ]
机构
[1] Samsung Adv Inst Technol, Yongin 446712, South Korea
关键词
carbon nanotubes; field emission; Raman spectra; transmission electron microscopy; work function; IN-SITU; TIP;
D O I
10.1063/1.3291108
中图分类号
O59 [应用物理学];
学科分类号
摘要
Carbon nanotubes in printed field emission arrays are known to be often damaged during field emission. A high-resolution transmission electron microscopy and Raman scattering spectra suggest that the degraded structure is mainly determined by electrical treatment conditions. A nonstationary alternating-current treatment has caused emitters to be thicker and fewer with loss of crystallinity but improved the emission brightness and uniformity, while a direct-current treatment has shown little influence. The experimental observations can be quantitatively explained by the analytical estimation on the apex radius as well as the work function using the Seppen-Katamuki chart from the Fowler-Nordheim characteristics.
引用
收藏
页数:3
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