Hierarchical CuCo2O4/CuO nanoflowers crosslinked with carbon nanotubes as an advanced electrode for supercapacitors?

被引:36
作者
Liu, Yafei [1 ]
Chang, Xiaoya [2 ]
Wang, Mengying [1 ]
Guo, Huinan [1 ]
Li, Weiqin [1 ]
Wang, Yijing [1 ]
机构
[1] Nankai Univ, Coll Chem, Renewable Energy Convers & Storage Ctr, Key Lab Adv Energy Mat Chem,Minist Educ, Tianjin 300071, Peoples R China
[2] Shenzhen Battery Dev Ctr BYD, Dept Electrochem Technol, FinDream Battery, Shenzhen 518000, Peoples R China
基金
中国国家自然科学基金;
关键词
Supercapacitor; CuCo2O4/CuO/carbon nanotubes; 3D hierarchical structure; ASYMMETRIC SUPERCAPACITORS; FACILE SYNTHESIS; ANODE MATERIAL; NI FOAM; PERFORMANCE; MORPHOLOGY; GRAPHENE; NANOCOMPOSITES; NANOSHEETS; COMPOSITE;
D O I
10.1016/j.jallcom.2021.159555
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The emerging CuCo2O4 is a promising electrode material for supercapacitors, while the low conductivity and volume expansion limit the specific capacity and rate performance. Here, a facile solvothermal method is used to synthesize hierarchical flower-like CuCo2O4/CuO. Then the CuCo2O4/CuO that crosslinked with carbon nanotubes could form a 3D conductive network and lead to a superior electrochemical performance. As-prepared material CuCo2O4/CuO/carbon nanotubes exhibit a specific capacitance of 1084 F g(-1) at 2 A g(-1) and excellent cycling stability of 97.8% retention after 9000 cycles. Moreover, the assembled asymmetric supercapacitor coupled with active carbon demonstrates an extraordinary cycling stability (86.8% after 9000 cycles). (C) 2021 Elsevier B.V. All rights reserved.
引用
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页数:9
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