Synthesis and crystal structure of the low-temperature modification of Li12Zn4(P2O7)5

被引:7
作者
Lapshin, A. E. [1 ]
Petrova, M. A. [1 ]
机构
[1] Russian Acad Sci, IV Grebenshchikov Silicate Chem Inst, St Petersburg 199034, Russia
关键词
lithium zinc phosphate; crystal structure; full-profile analysis of powders; NA2ZNP2O7; NA; LI;
D O I
10.1134/S108765961001013X
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The crystal structure of a low-temperature modification of the Li12Zn4(P2O7)(5) compound has been determined by full-profile analysis from the X-ray powder diffraction data. The compound crystallizes in the monoclinic crystal system (a = 5.130(1) , b = 13.454(1) , c = 8.205(1) , beta = 90.36(1)A degrees, space group P2(1)/n, Z = 4) and has a framework structure in which the zinc and lithium atoms statistically occupy equivalent positions.
引用
收藏
页码:75 / 79
页数:5
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