Synthesis and Synthesis of High-Performance Water- Reducing Agent for Polyglycolic Acid

被引:3
作者
Li, Xiaowei [1 ,2 ]
Wang, Hao [3 ]
机构
[1] Xijing Univ, Civil Engn Coll, Xian, Shaanxi, Peoples R China
[2] Xijing Univ, Shaanxi Key Lab Safety & Durabil Concrete Struct, Xian, Shaanxi, Peoples R China
[3] Jishou Univ, Sch Civil Engn & Architecture, Zhangjiajie, Hunan, Peoples R China
关键词
Polyether polycarboxylic acid high performance water reducer; dosage of KPA; reaction time; branched length and density of PR;
D O I
10.1080/10584587.2021.1911220
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In this paper, using maleic anhydride (MA), allyl polyethylene glycol (AP), methyl allyl sulfonate (SM) as monomer and ammonia persulfate (KPA) as initiator, a polyether high-performance water-reducing agent for polyglycolic acid (PR) on good compatibility in sulphoaluminate cement (SAC) was synthesized by solution polymerization and orthogonal design. And the effects of various factors (reaction time, branched length and density of PR etc.) on the performance of PR were also studied. Results show that the optimum formula was as follows: the polymerization degree of AP was 56, the mass molar ratio of three monomers was n (MA): n (AP): n (SM) = 3:2:1, the amount of AP accounted for 9% of the total molar content of monomer, the reaction temperature was 65 degrees C, and the reaction time was 5 h.
引用
收藏
页码:14 / 23
页数:10
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