Effect of ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide on the properties of poly(glycidyl methacrylate) based solid polymer electrolytes

被引：18

作者：

Nabilah, M. R. N. ^{[1
]}

Alwi, M. A. ^{[1
]}

Su'ait, M. S. ^{[2
]}

Imperiyka, M. ^{[3
]}

Hanifah, S. A. ^{[1
]}

Ahmad, A. ^{[1
,2
]}

Hassan, N. H. ^{[1
]}

Rahman, M. Y. A. ^{[4
]}

机构：

[1] Univ Kebangsaan Malaysia, Fac Sci & Technol, Sch Chem Sci & Food Technol, Bangi 43600, Selangor, Malaysia

[2] Univ Kebangsaan Malaysia, SERI, Bangi 43600, Selangor, Malaysia

[3] Univ Benghazi, Fac Arts & Sci, Kufra Campus, Al Kufrah, Libya

[4] Univ Kebangsaan Malaysia, Inst Microengn & Nanoelect IMEN, Bangi 43600, Selangor, Malaysia

来源：

RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2016年 / 52卷 / 04期

关键词：

1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide; ionic liquid; poly(glycidyl methacrylate); solid polymer electrolyte; THERMAL-DEGRADATION; MECHANICAL-PROPERTIES; BLEND ELECTROLYTES; LITHIUM BATTERIES; CONDUCTIVITY; PMMA; TETRAFLUOROBORATE; COPOLYMERS; SALT;

D O I：

10.1134/S1023193516040091

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A free standing polymer electrolytes films, containing poly(glycidyl methacrylate) (PGMA) as the polymer host, lithium perchlorate (LiClO4), and ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl) imide [Bmim][TFSI] as a plasticizer was successfully prepared via the solution casting method. The XRD analysis revealed the amorphous nature of the electrolyte. ATR-FTIR and thermal studies confirmed the interaction and complexation between the polymer host and the ionic liquid. The maximum ionic conductivity of the solid polymer electrolyte was found at 2.56 x 10(-5) S cm(-1) by the addition of 60 wt % [Bmim][TFSI] at room temperature and increased up to 3.19 x 10(-4) S cm(-1) at 373 K, as well as exhibited a transition of temperature dependence of conductivity: Arrhenius-like behavior at low and high temperatures.

引用

页码：362 / 373

页数：12

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