Vacuum-assisted continuous flow electroless plating approach for high performance Pd membrane deposition on ceramic hollow fiber lumen

被引:21
作者
Ji, Yun [1 ]
Sun, Haofeng [1 ]
Wang, Xiaobin [1 ]
Yang, Tengfei [1 ]
Xue, Zhiwei [1 ]
Li, Claudia [2 ]
Yang, Naitao [1 ]
Sunarso, Jaka [2 ]
Liu, Shaomin [3 ]
机构
[1] Shandong Univ Technol, Sch Chem & Chem Engn, Zibo 255000, Peoples R China
[2] Swinburne Univ Technol, Fac Engn Comp & Sci, Res Ctr Sustainable Technol, Jalan Simpang Tiga, Sarawak 93350, Malaysia
[3] Beijing Univ Chem Technol, Coll Chem Engn, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
Pd composite hollow fiber membrane; Membrane stability; Vacuum and continuous flow growth; Benzene to phenol; CATALYTIC PALLADIUM MEMBRANE; PD/AL2O3 COMPOSITE MEMBRANES; ONE-STEP HYDROXYLATION; HYDROGEN SEPARATION; ZIF-8; MEMBRANES; INNER-SURFACE; BENZENE; PHENOL; THIN; PERMEATION;
D O I
10.1016/j.memsci.2021.120207
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Pd-based membranes have wide applications in H-2-related fields given their excellent selectivity in H-2 separation. Despite their unique advantages, the fabrication of continuous and dense Pd membrane layer in the lumen side of the hollow fibers remains a great challenge. Herein, a vacuum-assisted continuous flow electroless plating (VCFELP) approach was developed to deposit a 4 mu m-thick compact Pd membrane layer on the lumen (i.e., inner surface) of YSZ-Al2O3 composite hollow fiber with outer and inner diameter of 1.5 and 1.0 mm, respectively. The Pd membrane displayed hydrogen flux of ~0.075 mol m(-2) s(-1) at 773 K and the nitrogen was undetectable through bubble flow meter and gas chromatograph. Furthermore, the stability and durability of the Pd membrane were significantly improved by the VCFELP approach with the aid of vacuum and continuous flow system. The outstanding membrane stability was verified by the 240-h long-term operation, with up to 24 cycles of H-2-N-2 gas exchange tests, 40 thermal cycle tests (from high to low temperature) and 20 pressure cycle tests. Furthermore, the Pd membrane showed sufficient stability and excellent reaction performance during the 120-h reaction run in the one-step oxidation of benzene to phenol using hydrogen and oxygen as co-reactants, achieving the benzene conversion and phenol selectivity of 23.5% and 91.6%, respectively.
引用
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页数:10
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