Concise Approach to Pupukeanane Skeleton: Synthetic Study of Chloropupukeananin

被引：34

作者：

Suzuki, Takahiro ^{[1
]}

Kobayashi, Susumu ^{[1
]}

机构：

[1] Tokyo Univ Sci RIKADAI, Fac Pharmaceut Sci, Noda, Chiba 2788510, Japan

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 13期

关键词：

DIELS-ALDER APPROACH; HIGH-PRESSURE; PESTALOTIOPSIS-FICI; ORGANIC-SYNTHESIS; METABOLITES; 9-ISOCYANOPUPUKEANANE; (+/-)-2-PUPUKEANONE; REAGENTS; STRATEGY; ALLOMONE;

D O I：

10.1021/ol100935w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A concise synthesis of a highly functionalized chloropupukeananin (1) skeleton via a reverse electron-demand Diels-Alder reaction and intramolecular carbonyl-ene reaction sequence based on our proposed biosynthetic pathway is described.

引用

页码：2920 / 2923

页数：4

共 39 条

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