Luminescent europium(III)-β-diketonate complexes hosted in nanozeolite L as turn-on sensors for detecting basic molecules

被引:56
作者
Li, Peng [1 ]
Zhang, Yuzhao [2 ]
Wang, Yige [1 ]
Wang, Yanji [1 ]
Li, Huanrong [1 ]
机构
[1] Hebei Univ Technol, Sch Chem Engn & Technol, Tianjin 300130, Peoples R China
[2] Hebei Univ Technol, Sch Control Sci & Engn, Tianjin 300130, Peoples R China
基金
中国国家自然科学基金;
关键词
METAL-ORGANIC FRAMEWORK; IONIC LIQUIDS; ZEOLITES; EMITTERS;
D O I
10.1039/c4cc05635c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The luminescence efficiency of Eu3+-beta-diketonate complexes entrapped within the channels of nanozeolite L is severely decreased by the acidic environment in the channels. The neutralization of the acid sites can remarkably increase the luminescence efficiency due to the formation of complexes with high coordination numbers. Herein we report a simple, effective and robust luminescent sensor for detecting basic molecules (such as amines) based on the above observations.
引用
收藏
页码:13680 / 13682
页数:3
相关论文
共 28 条
[1]   Proton activity inside the channels of zeolite L [J].
Albuquerque, Rodrigo Q. ;
Calzaferri, Gion .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (32) :8939-8952
[2]   Host-guest antenna materials [J].
Calzaferri, G ;
Huber, S ;
Maas, H ;
Minkowski, C .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (32) :3732-3758
[3]  
Cao PP, 2011, J MATER CHEM, V21, P2709, DOI 10.1039/C0JM03798B
[4]   Luminescent open metal sites within a metal-organic framework for sensing small molecules [J].
Chen, Banglin ;
Yang, Yu ;
Zapata, Fatima ;
Lin, Guannan ;
Qian, Guodong ;
Lobkovsky, Emil B. .
ADVANCED MATERIALS, 2007, 19 (13) :1693-+
[5]   Lanthanide metal-organic frameworks for luminescent sensing and light-emitting applications [J].
Cui, Yuanjing ;
Chen, Banglin ;
Qian, Guodong .
COORDINATION CHEMISTRY REVIEWS, 2014, 273 :76-86
[6]   Luminescent Functional Metal-Organic Frameworks [J].
Cui, Yuanjing ;
Yue, Yanfeng ;
Qian, Guodong ;
Chen, Banglin .
CHEMICAL REVIEWS, 2012, 112 (02) :1126-1162
[7]  
Dang S, 2012, J MATER CHEM, V22, P16920, DOI [10.1039/c2jm32661, 10.1039/c2jm32661b]
[8]   Photostable and efficient red-emitters based on zeolite L crystals [J].
Ding, Yanxia ;
Wang, Yige ;
Li, Huanrong ;
Duan, Zhongyu ;
Zhang, Haohui ;
Zheng, Youxuan .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (38) :14755-14759
[9]   Hydrogen-bond acidic polymers for chemical vapor sensing [J].
Grate, Jay W. .
CHEMICAL REVIEWS, 2008, 108 (02) :726-745
[10]   Metal-Organic Framework Materials as Chemical Sensors [J].
Kreno, Lauren E. ;
Leong, Kirsty ;
Farha, Omar K. ;
Allendorf, Mark ;
Van Duyne, Richard P. ;
Hupp, Joseph T. .
CHEMICAL REVIEWS, 2012, 112 (02) :1105-1125