Modeling of copper ion removal from aqueous solutions using modified silica beads

被引:5
作者
Lee, H [1 ]
Kim, J [1 ]
Yi, J [1 ]
机构
[1] Seoul Natl Univ, Sch Chem Engn, Seoul 151742, South Korea
关键词
modeling; copper; non-equilibrium; equilibrium; silica; LIX84;
D O I
10.1080/00986440008912814
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Silica beads, containing 2-hydroxy-5-nonylacetophenoncoxime (LIX84) were prepared in order to examine the removal of copper ions from aqueous waste solutions. The process for copper ion removal using the modified silica beads was mathematically modeled using both a nonequilibrium model and an equilibrium model. The external mass transfer coefficient and effective diffusivity inside the bead pore were estimated by matching the experimental data and predicted values from the model, and the results were compared. The results of the two models were similar and in good agreement because of the relatively faster reaction rate than mass transfer rate. Sensitivity analyses showed that the external mass transfer has more influence on the copper ion removal system because of hydrophobic effects.
引用
收藏
页码:37 / 55
页数:19
相关论文
共 23 条
[1]   MODELING THE TRANSPORT OF SOLUTES INFLUENCED BY MULTIPROCESS NONEQUILIBRIUM [J].
BRUSSEAU, ML ;
JESSUP, RE ;
RAO, PSC .
WATER RESOURCES RESEARCH, 1989, 25 (09) :1971-1988
[2]   ADSORPTION WITH CHEMICAL-REACTION IN A SINGLE MODIFIED-CARBON PELLET [J].
CHATTERJEE, SG ;
TIEN, C .
CHEMICAL ENGINEERING SCIENCE, 1989, 44 (10) :2283-2294
[3]   TRANSPORT OF CO(II) IONS THROUGH DI(2-ETHYLHEXYL) PHOSPHORIC ACID-CCL4 SUPPORTED LIQUID MEMBRANES [J].
CHAUDRY, MA ;
MALIK, MT ;
ALI, A .
SEPARATION SCIENCE AND TECHNOLOGY, 1990, 25 (11-12) :1161-1174
[4]   Equilibrium and kinetic studies of copper ion uptake by calcium alginate [J].
Chen, JP ;
Tendeyong, F ;
Yiacoumi, S .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1997, 31 (05) :1433-1439
[5]  
CUSSLER EL, 1984, DIFFUSION, P36
[6]   USER-ORIENTED BATCH REACTOR SOLUTIONS TO THE HOMOGENEOUS SURFACE-DIFFUSION MODEL [J].
HAND, DW ;
CRITTENDEN, JC ;
THACKER, WE .
JOURNAL OF ENVIRONMENTAL ENGINEERING-ASCE, 1983, 109 (01) :82-101
[7]  
*IMSL, 1986, US MAN, V3, P835
[8]   EXTRACTIVE SEPARATION OF GROUP IVB ELEMENTS - ANALYSIS OF ALLOY SAMPLES [J].
KAKADE, SM ;
SHINDE, VM .
TALANTA, 1995, 42 (04) :635-639
[9]   Breakthrough curve for adsorption of mercury(II) on polyaminated highly porous chitosan beads [J].
Kawamura, Y ;
Yoshida, H ;
Asai, S ;
Tanibe, H .
WATER SCIENCE AND TECHNOLOGY, 1997, 35 (07) :97-105
[10]   A UNIFIED APPROACH FOR MOMENTS IN CHROMATOGRAPHY [J].
LEE, WC ;
HUANG, SH ;
TSAO, GT .
AICHE JOURNAL, 1988, 34 (12) :2083-2087