Direct Functionalization of C-H Bonds by Iron, Nickel, and Cobalt Catalysis

被引：177

作者：

Pototschnig, Gerit ^{[1
]}

Maulide, Nuno ^{[2
]}

Schnuerch, Michael ^{[3
]}

机构：

[1] CALTECH, Warren & Katharine Schlinger Lab Chem & Chem Engn, Div Chem & Chem Engn, 1200 E Calif Blvd, Pasadena, CA 91125 USA

[2] Univ Vienna, Inst Organ Chem, Wahringerstr 38, A-1090 Vienna, Austria

[3] TU Wien, Inst Appl Synthet Chem, Getreidemarkt 9-163, A-1060 Vienna, Austria

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2017年 / 23卷 / 39期

关键词：

base metal catalysis; C-H activation; cobalt; iron; nickel; N-TYPE REACTIONS; TERMINAL ALKYNES; DIRECT ARYLATION; REGIOSELECTIVE HYDROHETEROARYLATION; COBALT(III)-CATALYZED SYNTHESIS; INTRAMOLECULAR HYDROACYLATION; AROMATIC CARBOXAMIDES; 2-STATE REACTIVITY; ALIPHATIC AMIDES; C(SP(3))-H BONDS;

D O I：

10.1002/chem.201605657

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Non-precious-metal-catalyzed reactions are of increasing importance in chemistry due to the outstanding ecological and economic properties of these metals. In the subfield of metal-catalyzed direct C-H functionalization reactions, recent years have shown an increasing number of publications dedicated to this topic. Nickel, cobalt, and last but not least iron, have started to enter a field which was long dominated by precious metals such as palladium, rhodium, ruthenium, and iridium. The present review article summarizes the development of iron-, nickel-, and cobalt-catalyzed C-H functionalization reactions until the end of 2016, and discusses the scope and limitations of these transformations.

引用

页码：9206 / 9232

页数：27

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