Cu(II)/TBAI-Catalyzed Esterification of Acid Hydrazides via C(sp3)-H Oxidative Coupling

被引：4
作者：
Liu, Guifeng [1 ,2 ]
Jin, Can [1 ,2 ]
Wu, Guomin [1 ,2 ]
机构：
[1] Chinese Acad Forestry, Key Lab Biomass Energy & Mat Jiangsu Prov, Key & Open Lab Forest Chem Engn,State Forestry Ad, Inst Chem Ind Forest Prod,Natl Engn Lab Biomass C, Nanjing 210042, Jiangsu, Peoples R China
[2] Chinese Acad Forestry, Res Inst New Technol, Beijing 10091, Peoples R China
来源：
SYNLETT | 2014年 / 25卷 / 20期
关键词：
Cu2+/TBAI cocatalysis; direct coupling; acid hydrazides; C-H FUNCTIONALIZATION; TERT-BUTYL HYDROPEROXIDE; BOND FUNCTIONALIZATION; TERMINAL ALKENES; NATURAL-PRODUCTS; LIGAND; COPPER; DEHYDROGENATION; ACTIVATION; CATALYST;
D O I：
10.1055/s-0034-1379478
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A Cu2+/TBAI-cocatalyzed allylic ester synthesis was developed, which allows a direct coupling of acid hydrazides and cycloalkanes. This process makes use of commercially available, inexpensive, and abundant starting materials. Based on the extensive experimental data, a plausible radical mechanism was suggested.
引用
收藏
页码：2908 / 2912
页数：5
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