Rhenium-catalyzed reaction of carbonyl compounds with ketene silyl acetals

被引：17

作者：

Nishiyama, Yutaka ^{[1
]}

Kaiba, Kenta ^{[1
]}

Umeda, Rui ^{[1
]}

机构：

[1] Kansai Univ, Fac Chem Mat & Bioengn, Dept Chem & Mat Engn, Osaka 5648680, Japan

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 05期

关键词：

ENANTIOSELECTIVE MUKAIYAMA ALDOL; LEWIS-ACID; MICHAEL REACTIONS; ENOL ETHERS; PARALLEL RECOGNITION; ALLYLATION; COMPLEXES; ALDEHYDES; DIFFERENTIATION; ALKYLATION;

D O I：

10.1016/j.tetlet.2009.11.109

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It was found that rhenium complex is an effective catalyst for the reaction of carbonyl compounds with ketene silyl acetals. A wide range of beta-silyloxy esters is obtained by the treatment of carbonyl compounds with ketene silyl acetals in the presence of a catalytic amount of ReBr(CO)(5) in moderate to good yields. (c) 2009 Elsevier Ltd. All rights reserved.

引用

页码：793 / 795

页数：3

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