Application of multidimensional gas chromatography to the enantioselective characterisation of the essential oil of Eupatorium buniifolium Hooker et Arnott

被引:20
作者
Lorenzo, D
Paz, D
Davies, P
Villamil, J
Vila, R
Cañigueral, S
Dellacassa, E
机构
[1] Univ Republica, Fac Quim, Catedra Farmacognosia & Prod Nat, CP-11800 Montevideo, Uruguay
[2] Estac Expt INIA Las Brujas, Canelones, Uruguay
[3] Univ Barcelona, Fac Farm, Unitat Farmacol & Farmacognosia, E-08028 Barcelona, Spain
关键词
enantioselective gas chromatography; essential oil; Eupatorium buniifolium; chilca; Asteraceae;
D O I
10.1002/pca.808
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The qualitative and quantitative composition of the essential oil from aerial parts of Eupatorium buniifolium Hooker et Arnott (Asteraceae) has been investigated for the first time. The essential oils were obtained by steam distillation of leaves and analysed by GC-MS; 44 components were identified. Monoterpene and sesquiterpene hydrocarbons, especially alpha-pinene (14.7%), beta-elemene (12.2%), germacrene D (11.5%), trans-beta-guaiene (6.5%) and (E)-caryophyllene (4.3%), were the major constituents found in the oils. The characterisation of E. buniifolium by enantioselective GC was performed by evaluation of the enantiomeric ratios of alpha-pinene, sabinene, beta-pinene, limonene, terpinen-4-ol and germacrene D. Copyright (C) 2005 John Wiley Sons, Ltd.
引用
收藏
页码:39 / 44
页数:6
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