A large barocaloric effect associated with paramagnetic martensitic transformation in Co50Fe2.5V31.5Ga16 quaternary Heusler alloy

被引:36
作者
Liu, Hongwei [1 ,2 ,3 ]
Li, Zhe [2 ,3 ]
Zhang, Yuanlei [2 ,3 ]
Ni, Zhenting [1 ,2 ,3 ]
Xu, Kun [2 ,3 ]
Liu, Yongsheng [1 ]
机构
[1] Shanghai Univ Elect Power, Dept Phys, Shanghai 200090, Peoples R China
[2] Qujing Normal Univ, Yunnan Higher Educ Inst, Ctr Magnet Mat & Devices, Qujing 655011, Peoples R China
[3] Qujing Normal Univ, Yunnan Higher Educ Inst, Key Lab Adv Funct & Low Dimens Mat, Qujing 655011, Peoples R China
基金
中国国家自然科学基金;
关键词
Heusler alloy; Martensitic transformation; Barocaloric effect; SHAPE-MEMORY; TRANSITION; PRESSURE;
D O I
10.1016/j.scriptamat.2019.10.003
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A martensitic transformation (MT) with paramagnetic behavior has been developed in Co50Fe2.5V31.5Ga16 quaternary Heusler alloy near room temperature. Accompanying the transformation, this alloy shows a good two-way shape memory effect, which results in a considerable relative volume change between two phases. Because of this, it has been also found that the MT is strongly sensitive to the applied hydrostatic pressure. By utilizing an indirectly estimated method, the obtained maximum reversible isothermal entropy (AST) and adiabatic temperature change (Delta T-ad) resulted from hydrostatic pressure induced MT, respectively, achieve similar to 31 J/kg K and 6 K under 5 kbar, performing a large barocaloric effect. (C) 2019 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:1 / 5
页数:5
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