Chiral Nanoscale Metal-Organic Tetrahedral Cages: Diastereoselective Self-Assembly and Enantioselective Separation

被引：183
|
作者：
Liu, Taifeng
Liu, Yan
Xuan, Weimin
Cui, Yong [1 ]
机构：
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 24期
关键词：
chiral resolution; chirality; host-guest systems; inclusion compounds; self-assembly; ABSOLUTE CONFIGURATION; COMPLEXES; LIGANDS; RECOGNITION; CHEMISTRY; DESIGN; METATHESIS; REACTIVITY; RESOLUTION; CATALYSIS;
D O I：
10.1002/anie.201000416
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Cage rage: Chiral tetrahedral cages are diastereoselectively self-assembled from enantiopure C2-symmetric biphenyl bis(β-diketonate) linkers and C3-symmetric octahedral Fe3+ or Ca3+ ions (see picture; Fe purple, C blue, O red; cavity shown as an orange sphere). The porous polyhedra exhibit metal-dependent chiroptical behavior and act as hosts for the crystallization separation of racemic alcohols with up to 99.5% ee. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4121 / 4124
页数：4
相关论文
共 50 条
  • [31] Study of self-assembly of mixed-ligand metal-organic cages by high-resolution mass spectrometry
    Tong, Kang
    Jia, Jia
    Huang, Rongfu
    Luo, Jin
    MATERIALS ADVANCES, 2024, 5 (13): : 5394 - 5397
  • [32] Confinement Self-Assembly of Metal-Organic Cages within Mesoporous Carbon for One-Pot Sequential Reactions
    Zhu, Fan-Fan
    Chen, Li-Jun
    Chen, Shangjun
    Wu, Gui-Yuan
    Jiang, Wei-Ling
    Shen, Ji-Chuang
    Qin, Yi
    Xu, Lin
    Yang, Hai-Bo
    CHEM, 2020, 6 (09): : 2395 - 2406
  • [33] Decorated traditional cellulose with nanoscale chiral metal-organic frameworks for enhanced enantioselective capture
    Guo, Yun
    Zhang, Ling
    Wang, Kexuan
    Yu, Ajuan
    Zhang, Shusheng
    Ouyang, Gangfeng
    CHEMICAL COMMUNICATIONS, 2021, 57 (80) : 10343 - 10346
  • [34] Enantioselective Separation over a Chiral Biphenol-Based Metal-Organic Framework
    Abbas, Anees
    Wang, Zhao-Xi
    Li, Zijian
    Jiang, Hong
    Liu, Yan
    Cui, Yong
    INORGANIC CHEMISTRY, 2018, 57 (15) : 8697 - 8700
  • [35] Chiral DHIP-Based Metal-Organic Frameworks for Enantioselective Recognition and Separation
    Zhang, Jie
    Li, Zijian
    Gong, Wei
    Han, Xing
    Liu, Yan
    Cui, Yong
    INORGANIC CHEMISTRY, 2016, 55 (15) : 7229 - 7232
  • [36] Controlling the Self-Assembly of Metal-Cages organic and transdermal drug delivery
    Liu, Xiao-Chang
    Lin, Lin
    INORGANIC CHEMISTRY COMMUNICATIONS, 2021, 129
  • [37] Metal-organic container molecules through subcomponent self-assembly
    Ronson, Tanya K.
    Zarra, Salvatore
    Black, Samuel P.
    Nitschke, Jonathan R.
    CHEMICAL COMMUNICATIONS, 2013, 49 (25) : 2476 - 2490
  • [38] Probing Molecular Mechanisms of Self-Assembly in Metal-Organic Frameworks
    Biswal, Debasmita
    Kusalik, Peter G.
    ACS NANO, 2017, 11 (01) : 258 - 268
  • [39] Structural diversity of metal-organic self-assembly assisted by chlorine
    Xie, Lei
    Zhang, Chi
    Ding, Yuanqi
    E, Wenlong
    Yuan, Chunxue
    Xu, Wei
    CHEMICAL COMMUNICATIONS, 2017, 53 (62) : 8767 - 8769
  • [40] Self-assembly of colloidal metal-organic framework (MOF) particles
    Fonseca, Javier
    Meng, Lingxin
    Imaz, Inhar
    Maspoch, Daniel
    CHEMICAL SOCIETY REVIEWS, 2023, 52 (07) : 2528 - 2543
12345