Chiral Nanoscale Metal-Organic Tetrahedral Cages: Diastereoselective Self-Assembly and Enantioselective Separation

被引：184

作者：

Liu, Taifeng

Liu, Yan

Xuan, Weimin

Cui, Yong ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 24期

关键词：

chiral resolution; chirality; host-guest systems; inclusion compounds; self-assembly; ABSOLUTE CONFIGURATION; COMPLEXES; LIGANDS; RECOGNITION; CHEMISTRY; DESIGN; METATHESIS; REACTIVITY; RESOLUTION; CATALYSIS;

D O I：

10.1002/anie.201000416

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Cage rage: Chiral tetrahedral cages are diastereoselectively self-assembled from enantiopure C2-symmetric biphenyl bis(β-diketonate) linkers and C3-symmetric octahedral Fe3+ or Ca3+ ions (see picture; Fe purple, C blue, O red; cavity shown as an orange sphere). The porous polyhedra exhibit metal-dependent chiroptical behavior and act as hosts for the crystallization separation of racemic alcohols with up to 99.5% ee. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4121 / 4124

页数：4

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