Synthesis, Structural Characterization, and Carbonyl Addition Reactivity of a Terminal Cerium(III) Acetylide Complex

被引：9
|
作者：
Kim, Jee Eon [1 ]
Weinberger, David S. [1 ]
Carroll, Patrick J. [1 ]
Schelter, Eric J. [1 ]
机构：
[1] Univ Penn, Dept Chem, P Roy & Diana T Vagelos Labs, Philadelphia, PA 19104 USA
来源：
ORGANOMETALLICS | 2014年 / 33卷 / 21期
基金：
美国国家科学基金会;
关键词：
X-RAY; EQUILIBRIUM ACIDITIES; GRIGNARD-REAGENTS; BOND FORMATION; LANTHANIDE; ORGANOLANTHANIDE; LIGANDS; HALIDES;
D O I：
10.1021/om500899z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We report the first structurally characterized terminal Ce(III) acetylide complex, Na[Ce(C=CPh)(bdmmp)(3)] (2), isolated from the salt metathesis of NaC=CPh with Na[Ce(OTf)(bdmmp)(3)] (1; bdmmp = 2,6-bis(dimethylamino)-4-methylphenolate). Compound 2 inserted acetophenone to form the tertiary alkoxide complex Na[Ce(OC(Me)(Ph)C=CPh)(bdmmp)(3)] (4), rather than forming an enolate product. To the best of our knowledge, complexes 2 and 4 are the first structurally characterized products that exhibit carbonyl group insertion into a CeC bond, affording new information on an important class of organocerium reagents.
引用
收藏
页码：5948 / 5951
页数：4
相关论文
共 50 条
  • [41] Synthesis and structural characterization of titanium aminotroponiminate complexes and their reactivity towards carbon monoxide and carbonyl compounds.
    Steinhuebel, DP
    Lippard, SJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U5 - U5
  • [42] Trinuclear copper(I) acetylide complexes bearing carbonyl moiety: Synthesis, characterization, and photophysical properties
    Zhang, Mei
    Su, Bo-Chao
    Li, Cheng-Luan
    Shen, Yong
    Lam, Chi-Keung
    Feng, Xiao-Long
    Chao, Hsiu-Yi
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (13) : 2654 - 2659
  • [43] Synthesis, characterization and reactivity of group ten phosphinoferrocene carbonyl complexes
    Kober, Erin
    Schreiner, Serge
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [44] Synthesis and Characterization of a Bridging Cerium(IV) Nitride Complex
    Wilson, Henry H.
    Yu, Xiaojuan
    Cheisson, Thibault
    Smith, Patrick W.
    Pandey, Pragati
    Carroll, Patrick J.
    Minasian, Stefan G.
    Autschbach, Jochen
    Schelter, Eric J.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (02) : 781 - 786
  • [45] Structural elucidation of a methylenation reagent of esters: synthesis and reactivity of a dinuclear titanium(iii) methylene complex
    Kurogi, Takashi
    Kuroki, Kaito
    Moritani, Shunsuke
    Takai, Kazuhiko
    CHEMICAL SCIENCE, 2021, 12 (10) : 3509 - 3515
  • [46] Solvothermal synthesis and structural characterization of a novel erbium(III)-carboxylate polymeric complex
    Bo, Q. B.
    Sun, Z. X.
    Sheng, Y. L.
    Zhang, Z. W.
    Sun, G. X.
    Chen, C. L.
    Li, Y. X.
    Wang, D. Q.
    STRUCTURAL CHEMISTRY, 2006, 17 (06) : 609 - 615
  • [47] Solvothermal synthesis and structural characterization of a novel erbium(III)-carboxylate polymeric complex
    Q. B. Bo
    Z. X. Sun
    Y. L. Sheng
    Z. W. Zhang
    G. X. Sun
    C. L. Chen
    Y. X. Li
    D. Q. Wang
    Structural Chemistry, 2006, 17 : 609 - 615
  • [48] A NOVEL DECACOORDINATE CERIUM COMPLEX - THE SYNTHESIS AND CHARACTERIZATION OF BIS[2,6-DIACETYLPYRIDINE BIS(SEMICARBAZONE)] CERIUM(III) PERCHLORATE TRIHYDRATE
    THOMAS, JE
    PALENIK, GJ
    INORGANICA CHIMICA ACTA-LETTERS, 1980, 44 (06): : L303 - L304
  • [49] SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF TUNGSTEN OXO-OLEFIN AND OXO-CARBONYL COMPOUNDS - SYNTHESIS BY OXIDATIVE ADDITION OF CARBON-DIOXIDE
    MAYER, JM
    SU, FM
    BRYAN, JC
    GEIB, SJ
    RHEINGOLD, AL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 192 : 268 - INOR
  • [50] Cyclic tetranuclear iron-carbonyl complex containing thiobisbenzenethiolate ligands: Synthesis and structural characterization
    Johnson, Shakeena L.
    Gerasimchuk, Nikolay N.
    Mebi, Charles A.
    INORGANICA CHIMICA ACTA, 2018, 477 : 306 - 311
12345